Amrani, Alon and Ma, Qisheng and Ahmad, Ward Said and Aizenshtat, Zeev and Tang, Yongchung (2008) Sulfur isotope fractionation during incorporation of sulfur nucleophiles into organic compounds. Chemical Communications, 2008 (11). pp. 1356-1358. ISSN 1359-7345 http://resolver.caltech.edu/CaltechAUTHORS:AMRcc08
![[img]](http://authors.library.caltech.edu/style/images/fileicons/application_pdf.png)
|
PDF
See Usage Policy. 494Kb | |
![[img]](http://authors.library.caltech.edu/10101/2/AMRcc08.gif)
|
Cover Image
See Usage Policy. 7Kb | |
|
PDF (Supplementary Information)
See Usage Policy. 393Kb |
Use this Persistent URL to link to this item: http://resolver.caltech.edu/CaltechAUTHORS:AMRcc08
Abstract
34S enrichment is shown to occur during sulfurization reactions and for the first time conclusively attributed to an isotope equilibrium effect rather than selective addition of 34S enriched nucleophiles.
| Item Type: | Article |
|---|---|
| Additional Information: | © Royal Society of Chemistry 2008. Received (in Cambridge, UK) 5th November 2007, Accepted 2nd January 2008. First published as an Advance Article on the web 16th January 2008. The authors wish to thank David Sprinzak (Caltech) for help with MATLAB programing and Alex Sessions (Caltech) and Dmitri Gelman (Hebrew University) for helpful comments and discussions on an earlier version of this paper. Electronic supplementary information (ESI) available: Experimental and molecular modeling procedures, optimized coordinates for all structures, supplementary data for Tables 1–3, GC-MS trace for some of the products. See DOI: 10.1039/b717113g |
| Subject Keywords: | polysulfide anions; Michael addition; isotope fractionation |
| Record Number: | CaltechAUTHORS:AMRcc08 |
| Persistent URL: | http://resolver.caltech.edu/CaltechAUTHORS:AMRcc08 |
| Alternative URL: | http://dx.doi.org/10.1039/b717113g |
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. |
| ID Code: | 10101 |
| Collection: | CaltechAUTHORS |
| Deposited By: | Archive Administrator |
| Deposited On: | 14 Apr 2008 |
| Last Modified: | 26 Dec 2012 09:56 |
Repository Staff Only: item control page
