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An Absorption Band of Formaldoxime at lambda9572

Zumwalt, Lloyd R. and Badger, Richard M. (1939) An Absorption Band of Formaldoxime at lambda9572. Journal of Chemical Physics, 7 (4). pp. 235-237. ISSN 0021-9606. http://resolver.caltech.edu/CaltechAUTHORS:ZUMjcp39b

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Abstract

The third harmonic of the O [Single Bond] H band in formaldoxime vapor has been found to lie at lambda9572 (10,444.1 cm^—1) and under high dispersion has been resolved and found to resemble a parallel band of a symmetric rotator. Owing to the weakness of the lines near the center of the band a definitely unique rotational analysis could not be made but the harmonic mean of the two larger moments of inertia appears to lie between the limits 73.3 and 76.6×10^—40 g cm^2. The hydroxyl hydrogen does not rotate freely and indeed its torsional oscillation appears not to have a very low frequency. It is not possible to locate this hydrogen uniquely until other parameters of the molecule have been determined by electron diffraction. The possible effect of resonance on the O [Single Bond] H frequency is discussed.


Item Type:Article
Additional Information:Copyright © 1939 American Institute of Physics. Received February 13, 1939. Contribution from the Gates and Crellin Laboratories of Chemistry, California Institute of Technology, Pasadena, California, number 681.
Record Number:CaltechAUTHORS:ZUMjcp39b
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:ZUMjcp39b
Alternative URL:http://dx.doi.org/10.1063/1.1750423
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:10436
Collection:CaltechAUTHORS
Deposited By: Archive Administrator
Deposited On:06 May 2008
Last Modified:26 Dec 2012 10:00

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