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The N[Single Bond]H Harmonic Bands of Pyrrole at lambda9900, and the Structure of the Pyrrole Molecule

Zumwalt, Lloyd R. and Badger, Richard M. (1939) The N[Single Bond]H Harmonic Bands of Pyrrole at lambda9900, and the Structure of the Pyrrole Molecule. Journal of Chemical Physics, 7 (8). pp. 629-630. ISSN 0021-9606. http://resolver.caltech.edu/CaltechAUTHORS:ZUMjcp39c

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Abstract

In their study of the infra-red absorption of organic substances in carbon tetrachloride solution Wulf and Liddell (1) found that the strong second harmonic N-H band of pyrrole is accompanied by a weak satellite which lies approximately 50 cm^-1 to the long wave side and has roughly one-twentieth the intensity of the main band. The main band has been attributed by Pauling (2) to a planar pyrrole molecule and the weak satellite to a second molecular species in which the imino hydrogen lies out of the plane of the other atoms.


Item Type:Article
Additional Information:Copyright © 1939 American Institute of Physics. Received June 24, 1939.
Record Number:CaltechAUTHORS:ZUMjcp39c
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:ZUMjcp39c
Alternative URL:http://dx.doi.org/10.1063/1.1750501
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:10437
Collection:CaltechAUTHORS
Deposited By: Archive Administrator
Deposited On:06 May 2008
Last Modified:26 Dec 2012 10:00

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