Badger, Richard M. and Zumwalt, Lloyd R. (1938) The Band Envelopes of Unsymmetrical Rotator Molecules. I. Calculation of the Theoretical Envelopes. Journal of Chemical Physics, 6 (11). pp. 711-717. ISSN 0021-9606 http://resolver.caltech.edu/CaltechAUTHORS:BADjcp38
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Since the majority of molecules of chemical interest are too heavy to permit resolution of the rotational structure of the infra-red bands, it is of interest to find what information can be derived from a study of the band envelopes. Considerations of the type which Gerhard and Dennison have made for symmetrical molecules have been extended to the unsymmetrical rotator. By the use of an approximation method the envelopes of the three elementary types of band have been calculated for nine different sets of molecular parameters.
|Additional Information:||Copyright © 1938 American Institute of Physics. Received June 14, 1938. Contribution from the Gates and Crellin Laboratories of Chemistry, California Institute of Technology, No. 653.|
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|Deposited On:||06 May 2008|
|Last Modified:||26 Dec 2012 10:00|
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