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The Infrared Spectrum and Internuclear Distances of Methyl Acetylene

Badger, Richard M. and Bauer, Simon H. (1937) The Infrared Spectrum and Internuclear Distances of Methyl Acetylene. Journal of Chemical Physics, 5 (7). p. 599. ISSN 0021-9606. http://resolver.caltech.edu/CaltechAUTHORS:BADjcp37c

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Abstract

A parallel type band of methyl acetylene in the photographic infrared has recently been investigated Herzberg, Patat and Verleger (1) who were able to obtain from it an accurate value of the large moment of inertia of the molecule. Assuming that all parameters except the C-C single bond distance have the value which have been found in other molecules they were obliged to conclude that this distance is about 1.463 Å. This conclusion seems rather remarkable since the C-C single bond bond distance has been found to be approximately 1.54 Å in a number of molecules, and it seemed worth while to check the result.


Item Type:Article
Additional Information:Copyright © 1937 American Institute of Physics. Received May 10, 1937. The experimental work here described was a part of a program of research made possible by a grant-in-aid from the National Research Council to one of us (R.M.B.). We are indebted to Mr. H.D. Springall for the methyl acetylene used in the investigation.
Record Number:CaltechAUTHORS:BADjcp37c
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:BADjcp37c
Alternative URL:http://dx.doi.org/10.1063/1.1750081
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:10453
Collection:CaltechAUTHORS
Deposited By: Archive Administrator
Deposited On:06 May 2008
Last Modified:26 Dec 2012 10:00

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