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Abstraction fraction in the reaction of deuterium atoms with HBr and HI

Persky, Avigdor and Kuppermann, Aron (1974) Abstraction fraction in the reaction of deuterium atoms with HBr and HI. Journal of Chemical Physics, 61 (12). pp. 5035-5039. ISSN 0021-9606. http://resolver.caltech.edu/CaltechAUTHORS:PERjcp74

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Abstract

The reaction between D atoms and HX molecules (X=Br or I) may result in either abstraction of H atoms to yield HD+X or exchange of H atoms to yield DX+H. This reaction was studied at 300°K by photolyzing HX+DX+He mixtures with monochromatic light at two wavelengths. It was found that the abstraction fraction is 0.76±0.10 for X=Br and 0.88±0.08 for X = I. These results are discussed in terms of the dynamics of these reactions.


Item Type:Article
Additional Information:©1975 American Institute of Physics. Received 26 March 1974. Work supported in part by the U.S. Atomic Energy Commission, Rept. Code CALT-767P4-130. Arthur Amos Noyes Laboratory of Chemical Physics, Contribution No. 4863.
Record Number:CaltechAUTHORS:PERjcp74
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:PERjcp74
Alternative URL:http://dx.doi.org/10.1063/1.1681845
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:10648
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:29 May 2008
Last Modified:26 Dec 2012 10:03

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