Persky, Avigdor and Kuppermann, Aron (1974) Abstraction fraction in the reaction of deuterium atoms with HBr and HI. Journal of Chemical Physics, 61 (12). pp. 5035-5039. ISSN 0021-9606 http://resolver.caltech.edu/CaltechAUTHORS:PERjcp74
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Abstract
The reaction between D atoms and HX molecules (X=Br or I) may result in either abstraction of H atoms to yield HD+X or exchange of H atoms to yield DX+H. This reaction was studied at 300°K by photolyzing HX+DX+He mixtures with monochromatic light at two wavelengths. It was found that the abstraction fraction is 0.76±0.10 for X=Br and 0.88±0.08 for X = I. These results are discussed in terms of the dynamics of these reactions.
| Item Type: | Article |
|---|---|
| Additional Information: | ©1975 American Institute of Physics. Received 26 March 1974. Work supported in part by the U.S. Atomic Energy Commission, Rept. Code CALT-767P4-130. Arthur Amos Noyes Laboratory of Chemical Physics, Contribution No. 4863. |
| Record Number: | CaltechAUTHORS:PERjcp74 |
| Persistent URL: | http://resolver.caltech.edu/CaltechAUTHORS:PERjcp74 |
| Alternative URL: | http://dx.doi.org/10.1063/1.1681845 |
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. |
| ID Code: | 10648 |
| Collection: | CaltechAUTHORS |
| Deposited By: | Tony Diaz |
| Deposited On: | 29 May 2008 |
| Last Modified: | 26 Dec 2012 10:03 |
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