Heath, J. R. and Liu, Yuan and O'Brien, S. C. and Zhang, Qing-Ling and Curl, R. F. and Tittel, F. K. and Smalley, R. E. (1985) Semiconductor cluster beams: One and two color ionization studies of Six and Gex. Journal of Chemical Physics, 83 (11). pp. 5520-5526. ISSN 0021-9606 http://resolver.caltech.edu/CaltechAUTHORS:HEAjcp85
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Supersonic beams of clusters of Si and Ge atoms have been produced by laser vaporization followed by supersonic expansion in a helium carrier. The cluster beams were characterized by F2(7.9 eV) and ArF(6.4 eV) excimer laser ionization accompanied by time-of-flight mass analysis. In addition, the feasibility of a resonant two-photon ionization (R2PI) spectroscopic study was explored by two-color experiments involving initial excitation with the second (2.36 eV) and third (3.54 eV) harmonics of the Nd:YAG followed by excimer laser ionization. All two-photon ionization processes were found to produce extensive fragmentation of the larger clusters. The observed fragmentation pattern for the silicon and germanium clusters were remarkably similar to each other, but drastically different from that seen for metal clusters in the same apparatus. Unlike metal clusters, which tend to lose one atom at a time, these semiconductor clusters appear to fragment by a fission process, the daughter ions falling almost exclusively in the size range from 6 to 11 atoms. Time delay studies in the two-color experiments established that clusters of both Si and Ge have excited electronic states with lifetimes of approximately 100 ns. This again is dramatically different from the behavior found with metal clusters, and indicates the feasibility of R2PI spectroscopy on these cold semiconductor particles. The existence of such long-lived excited states indicates that there is probably an energy gap between the band of electronic states being excited and the ground electronic state.
|Additional Information:||Copyright © 1985 American Institute of Physics. Received 12 July 1985; accepted 21 August 1985. This work was supported by AROD Contract DAAG 29-85-K-0029 and grants C-071, C-586, and C-689 of theRobert A.Welch Foundation using supersonic beam equipment and lasers supported by the Department of Energy, Division of Chemical Science, and the National Science Foundation. [S.C.O'B. was a] Robert A. Welch postdoctoral fellow.|
|Subject Keywords:||SILICON, GERMANIUM, MOLECULAR BEAMS, SUPERSONIC FLOW, PHOTOIONIZATION, MULTI−PHOTON PROCESSES, SEMICONDUCTOR MATERIALS, BEAM PRODUCTION, ATOMIC CLUSTERS|
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|Deposited On:||06 Jun 2008|
|Last Modified:||26 Dec 2012 10:04|
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