Bowers, C. Russell and Weitekamp, Daniel P. (1986) Transformation of Symmetrization Order to Nuclear-Spin Magnetization by Chemical Reaction and Nuclear Magnetic Resonance. Physical Review Letters, 57 (21). pp. 2645-2648. ISSN 0031-9007 http://resolver.caltech.edu/CaltechAUTHORS:BOWprl86
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A method of obtaining very large nuclear-spin polarizations is proposed and illustrated by density-operator calculations. The prediction is that chemical reaction and rf irradiation can convert the scalar parahydrogen state into polarization of order unity on the nuclear spins of the products of molecular-hydrogen addition reactions. A means of extending the resultant sensitivity enhancement to other spins is proposed in which the transfer of order occurs through population differences not associated with magnetization.
|Additional Information:||©1986 The American Physical Society. Received 2 July 1986. The authors thank the Atlantic Richfield Foundation for partial support of this work.|
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|Deposited On:||13 Jun 2008|
|Last Modified:||26 Dec 2012 10:05|
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