CaltechAUTHORS
  A Caltech Library Service

Resonance effects in the 5σ photoionization of CO

Smith, Maile E. and Lynch, Diane L. and McKoy, Vincent (1986) Resonance effects in the 5σ photoionization of CO. Journal of Chemical Physics, 85 (11). pp. 6455-6459. ISSN 0021-9606. http://resolver.caltech.edu/CaltechAUTHORS:SMIjcp86

[img]
Preview
PDF - Published Version
See Usage Policy.

501Kb

Use this Persistent URL to link to this item: http://resolver.caltech.edu/CaltechAUTHORS:SMIjcp86

Abstract

We report vibrational branching ratios and vibrationally resolved photoelectron angular distributions for resonant photoionization of the 5sigma level of CO leading to X^2Σ+CO+. These results were obtained using frozen-core Hartree–Fock photoelectron continuum orbitals. These studies provide a clear quantitative picture of the role of the kσ shape resonance in the observed non-Franck–Condon behavior and useful insight into the interplay between this shape resonance and a valence-like autoionizing resonance around 23 eV.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1063/1.451425DOIUNSPECIFIED
http://link.aip.org/link/?JCPSA6/85/6455/1PublisherUNSPECIFIED
Additional Information:Copyright © 1986 American Institute of Physics. Received 18 August 1986; accepted 27 August 1986. This material is based on research supported by the National Science Foundation under Grant No. CHE-8521391. Arthur Amos Noyes Laboratory of Chemical Physics, Contribution No. 7435.
Funders:
Funding AgencyGrant Number
National Science FoundationCHE-8521391
Subject Keywords:CARBON MONOXIDE, PHOTOIONIZATION, RESONANCE, PHOTOELECTRON SPECTROSCOPY, ANGULAR DISTRIBUTION, VIBRATIONAL STATES, SPECTRAL RESOLUTION, BRANCHING RATIO
Other Numbering System:
Other Numbering System NameOther Numbering System ID
Arthur Amos Noyes Laboratory of Chemical Physics7435
Record Number:CaltechAUTHORS:SMIjcp86
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:SMIjcp86
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:11687
Collection:CaltechAUTHORS
Deposited By: Archive Administrator
Deposited On:18 Sep 2008 23:48
Last Modified:26 Dec 2012 10:18

Repository Staff Only: item control page