Suzuki, Sakae and Bumgarner, R. E. and Stockman, Paul A. and Green, Peter G. and Blake, Geoffrey A. (1991) Tunable far-infrared laser spectroscopy of deuterated isotopomers of Ar–H2O. Journal of Chemical Physics, 94 (1). pp. 824-825. ISSN 0021-9606 http://resolver.caltech.edu/CaltechAUTHORS:SUZjcp91
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Several far-infrared vibration-rotation-tunneling transitions have been measured in deuterated isotopomers of Ar–H2O for the first time. These experimental results will enable the generation of improved intermolecular potential energy surfaces for the Ar–H2O system when combined with existing microwave, far-infrared, and infrared data.
|Additional Information:||Copyright © 1991 American Institute of Physics. Received 24 August 1990; accepted 25 September 1990. This work was supported by grants from the Beckman Institute, the Packard Foundation, the Sloan Foundation, and the NSF (CHEM-8957228). Acknowledgment is also made to the Donors of the Petroleum Research Foundation, administered by the American Chemical Society, for partial support of this work. R.E. Bumgarner would like to acknowledge support from a Bantrell Fellowship. We would like to thank R.C. Cohen for numerous helpful discussions and for transmitting Ar-H2O predictions prior to publication, C.M. Lovejoy and D.J. Nesbitt for communication of their IR and FIR predictions prior to publication, and G. Fraser, F. Lovas, and R. Suenram for access to their extensive microwave data. [G.A.B. was a] Packard Fellow, Sloan Fellow, and Presidential Young Investigator.|
|Subject Keywords:||INFRARED SPECTRA, ARGON COMPLEXES, WATER, MOLECULAR CLUSTERS, ARGON, ADDUCTS, VIBRATIONAL STATES, ROTATIONAL STATES, POTENTIAL ENERGY SURFACES, FAR INFRARED RADIATION|
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|Deposited On:||20 Sep 2008 21:25|
|Last Modified:||26 Dec 2012 10:18|
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