Picosecond IVR dynamics of p-difluorobenzene and p-fluorotoluene in a molecular beam: Comparison with chemical timing data

Baskin, J. Spencer and Rose, Todd S. and Zewail, Ahmed H. (1988) Picosecond IVR dynamics of p-difluorobenzene and p-fluorotoluene in a molecular beam: Comparison with chemical timing data. Journal of Chemical Physics, 88 (2). pp. 1458-1459. ISSN 0021-9606 http://resolver.caltech.edu/CaltechAUTHORS:BASjcp88

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Abstract

We present in this Communication preliminary time-resolved fluorescence measurements of supersonaically cooled samples of pDFB and pFT. These measurements indicate that IVR in both cold molecules up to ~1600 cm^-1 of excess vibrational energy is substantially less than that reported for the same vibrational excitations in room temperature chemical timing studies.

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Article

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Copyright © 1988 American Institute of Physics. Received 1 October 1987; accepted 3 November 1987. This research was supported by Grant No. CHE-8512887 from the National Science Foundation. [A.H.Z. was a] John Simon Guggenheim Foundation Fellow. Arthur Amos Noyes Laboratory of Chemical Physics, Contribution No. 7660.

Funders:

Funding Agency	Grant Number
National Science Foundation	CHE-8512887
John Simon Guggenheim Foundation	UNSPECIFIED

Subject Keywords:

MOLECULAR BEAMS, SUPERSONIC FLOW, FLUORINATED AROMATIC HYDROCARBONS, VIBRATIONAL STATES, RELAXATION, FLUORESCENCE, COOLING, ENERGY TRANSFER

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Other Numbering System Name	Other Numbering System ID
Arthur Amos Noyes Laboratory of Chemical Physics	7660

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CaltechAUTHORS:BASjcp88

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11742

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22 Sep 2008 20:30

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