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Crystal structure of the yellow 1:2 molecular complex lumiflavin–bisnaphthalene-2,3-diol

Trus, Benes L. and Wells, Joe L. and Johnstone, Robert M. and Fritchie, Charles J., Jun. and Marsh, Richard E. (1971) Crystal structure of the yellow 1:2 molecular complex lumiflavin–bisnaphthalene-2,3-diol. Chemical Communications, 1971 (14). pp. 751-752. ISSN 0009-241X. http://resolver.caltech.edu/CaltechAUTHORS:TRUcc71

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Abstract

In the first molecular complex of the physiologically active neutral form of isoalloxazine studied, lumiflavin–bisnaphthalene-2,3-diol, each flavin is sandwiched between two naphthalenediol molecules with extensive overlap but a moderately large (3·44 Å) spacing, indicating at most weak charge-transfer interaction and in agreement with the yellow colour of the complex, nearly the same as that of the parent lumiflavin.


Item Type:Article
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http://dx.doi.org/10.1039/C29710000751DOIArticle
Additional Information:© Royal Society of Chemistry 1971. (Received, March 16th, 1971; Com. 307.) This investigation was supported by Public Health Service Research Grants from the National Institute of General Medical Sciences, National Institutes of Health.
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Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:TRUcc71
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Deposited On:22 Sep 2008 23:43
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