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Ion exchange kinetics. A nonlinear diffusion problem. II. Particle diffusion controlled exchange of univalent and bivalent ions

Plesset, M. S. and Helfferich, F. and Franklin, J. N. (1958) Ion exchange kinetics. A nonlinear diffusion problem. II. Particle diffusion controlled exchange of univalent and bivalent ions. Journal of Chemical Physics, 29 (5). pp. 1064-1069. ISSN 0021-9606. http://resolver.caltech.edu/CaltechAUTHORS:PLEjcp58

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Abstract

The differential equation derived previously which describes the particle diffusion controlled ion exchange between spherical beads of uniform size and a well-stirred solution is solved numerically for the exchange of monovalent ions for bivalent ions, and of bivalent ions for monovalent ions. The approach is based on the Nernst-Planck equations of ionic motion. Numerical results for six different mobility ratios are presented and discussed. They were obtained by use of a digital computer. An explicit equation approximating the numerical data is given.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1063/1.1744656DOIUNSPECIFIED
http://link.aip.org/link/?JCPSA6/29/1064/1PublisherUNSPECIFIED
Additional Information:© 1958 American Institute of Physics. Received July 7, 1958. This investigation was supported in part by the Office of Naval Research. We wish to express our gratitude to Mr. K.J. Hebert for his valuable assistance in the numerical integration and to Miss Z. Lindberg for computing the explicit approximation. Contribution No. 2374 from the Gates and Crellin Laboratories of Chemistry.
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Office of Naval ResearchUNSPECIFIED
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Gates and Crellin Laboratories of Chemistry2374
Record Number:CaltechAUTHORS:PLEjcp58
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:PLEjcp58
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:12002
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:18 Oct 2008 02:42
Last Modified:26 Dec 2012 10:25

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