Engstrom, J. R. and Weinberg, W. H. (1987) Summary Abstract: The oxidation of carbon monoxide on the Pt(110)-(1×2) surface: The influence of the adlayer composition on the reaction dynamics. Journal of Vacuum Science and Technology A, 5 (4). pp. 640-641. ISSN 0734-2101 http://resolver.caltech.edu/CaltechAUTHORS:ENGjvsta87a
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We have developed and employed the technique of surface temperature modulation to examine the dynamics of the oxidation of Ca on the Pt(110)-(1×2) surface . This technique permits a straightforward analysis of the energetics of elementary surface reactions even in the presence of strong nonlinearities, providing a decided advantage over competing techniques such as modulated molecular-beam reactive scattering. We shall emphasize here the coverage dependence of the kinetic rate parameters (Er and kr(2)Z)) that describe the elementary surface reaction CO(a) + O(a) → CO2 (g). These data will be compared briefly with results obtained previously concerning the coverage dependence of the energy retained in the translational  and internal [4,5] modes of the product CO2 molecule.
|Additional Information:||© 1987 American Vacuum Society. Received 18 September 1986; accepted 3 November 1986.|
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|Deposited On:||23 Oct 2008 05:43|
|Last Modified:||26 Dec 2012 10:26|
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