CaltechAUTHORS
  A Caltech Library Service

Secondary organic aerosol formation from photooxidation of naphthalene and alkylnaphthalenes: implications for oxidation of intermediate volatility organic compounds (IVOCs)

Chan, A. W. H. and Kautzman, K. E. and Chhabra, P. S. and Surratt, J. D. and Chan, M. N. and Crounse, J. D. and Kürten, A. and Wennberg, P. O. and Flagan, R. C. and Seinfeld, J. H. (2009) Secondary organic aerosol formation from photooxidation of naphthalene and alkylnaphthalenes: implications for oxidation of intermediate volatility organic compounds (IVOCs). Atmospheric Chemistry and Physics, 9 (9). pp. 3049-3060. ISSN 1680-7316. http://resolver.caltech.edu/CaltechAUTHORS:20090814-103729079

[img]
Preview
PDF - Published Version
Creative Commons Attribution.

2103Kb

Use this Persistent URL to link to this item: http://resolver.caltech.edu/CaltechAUTHORS:20090814-103729079

Abstract

Current atmospheric models do not include secondary organic aerosol (SOA) production from gas-phase reactions of polycyclic aromatic hydrocarbons (PAHs). Recent studies have shown that primary emissions undergo oxidation in the gas phase, leading to SOA formation. This opens the possibility that low-volatility gas-phase precursors are a potentially large source of SOA. In this work, SOA formation from gas-phase photooxidation of naphthalene, 1-methylnaphthalene (1-MN), 2-methylnaphthalene (2- MN), and 1,2-dimethylnaphthalene (1,2-DMN) is studied in the Caltech dual 28-m^3 chambers. Under high-NO_x conditions and aerosol mass loadings between 10 and 40μgm^(−3), the SOA yields (mass of SOA per mass of hydrocarbon reacted) ranged from 0.19 to 0.30 for naphthalene, 0.19 to 0.39 for 1-MN, 0.26 to 0.45 for 2-MN, and constant at 0.31 for 1,2-DMN. Under low-NO_x conditions, the SOA yields were measured to be 0.73, 0.68, and 0.58, for naphthalene, 1- MN, and 2-MN, respectively. The SOA was observed to be semivolatile under high-NO_x conditions and essentially nonvolatile under low-NO_x conditions, owing to the higher fraction of ring-retaining products formed under low-NO_x conditions. When applying these measured yields to estimate SOA formation from primary emissions of diesel engines and wood burning, PAHs are estimated to yield 3–5 times more SOA than light aromatic compounds over photooxidation timescales of less than 12 h. PAHs can also account for up to 54% of the total SOA from oxidation of diesel emissions, representing a potentially large source of urban SOA.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://www.atmos-chem-phys.net/9/3049/2009/acp-9-3049-2009.htmlPublisherArticle
https://dx.doi.org/10.5194/acp-9-3049-2009DOIArticle
ORCID:
AuthorORCID
Chan, A. W. H.0000-0001-7392-4237
Surratt, J. D.0000-0002-6833-1450
Chan, M. N.0000-0002-2384-2695
Crounse, J. D.0000-0001-5443-729X
Wennberg, P. O.0000-0002-6126-3854
Flagan, R. C.0000-0001-5690-770X
Seinfeld, J. H.0000-0003-1344-4068
Additional Information:© Author(s) 2009. This work is distributed under the Creative Commons Attribution 3.0 License. Received: 27 November 2008 – Published in Atmos. Chem. Phys. Discuss.: 21 January 2009. Revised: 15 April 2009. Accepted: 23 April 2009. Published: 12 May 2009. This research was funded by the Office of Science (BER), US Department of Energy Grant No. DE-FG02-05ER63983, US Environmental Protection Agency STAR Research Assistance Agreement No. RD-83374901 and US National Science Foundation grant ATM-0432377. This publication has not been formally reviewed by the EPA. The views expressed in this document are solely those of the authors and EPA does not endorse any products mentioned in this publication. The authors would like to thank D. R. Fitz for use of GC/NO2-PAN analyzer, L. D. Yee for assistance with running experiments, and C. E. Jordan for helpful discussion.
Funders:
Funding AgencyGrant Number
Department of Energy (DOE)DE-FG02-05ER63983
Environmental Protection Agency (EPA)RD-83374901
NSFATM-0432377
Record Number:CaltechAUTHORS:20090814-103729079
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20090814-103729079
Official Citation:Chan, A. W. H., Kautzman, K. E., Chhabra, P. S., Surratt, J. D., Chan, M. N., Crounse, J. D., Kürten, A., Wennberg, P. O., Flagan, R. C., and Seinfeld, J. H.: Secondary organic aerosol formation from photooxidation of naphthalene and alkylnaphthalenes: implications for oxidation of intermediate volatility organic compounds (IVOCs), Atmos. Chem. Phys., 9,3049-3060, 2009.
Usage Policy:This work is distributed under the Creative Commons Attribution 3.0 License.
ID Code:15029
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:14 Aug 2009 18:22
Last Modified:26 Apr 2017 18:37

Repository Staff Only: item control page