Young, Kenneth J. H. and Oxgaard, Jonas and Ess, Daniel H. and Meier, Steven K. and Stewart, Timothy and Goddard, William A., III and Periana, Roy A. (2009) Experimental realization of catalytic CH_4 hydroxylation predicted for an iridium NNC pincer complex, demonstrating thermal, protic, and oxidant stability. Chemical Communications, 2009 (22). pp. 3270-3272. ISSN 1359-7345 http://resolver.caltech.edu/CaltechAUTHORS:20090904-113907339
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Abstract
A discrete, air, protic, and thermally stable (NNC)Ir(III) pincer complex was synthesized that catalytically activates the CH bond of methane in trifluoroacetic acid; functionalization using NaIO_4 and KIO_3 gives the oxy-ester.
| Item Type: | Article | ||||||
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| Additional Information: | © Royal Society of Chemistry 2009. Received (in Cambridge, UK) 5th January 2009, Accepted 12th March 2009. First published on the web 23rd April 2009. We thank Chevron Energy Technology Company and Scripps Florida for financial support. Electronic supplementary information (ESI) available: Experimental details and DFT xyz coordinates. CCDC 697907–697909. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/b823303a | ||||||
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| Record Number: | CaltechAUTHORS:20090904-113907339 | ||||||
| Persistent URL: | http://resolver.caltech.edu/CaltechAUTHORS:20090904-113907339 | ||||||
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| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||
| ID Code: | 15617 | ||||||
| Collection: | CaltechAUTHORS | ||||||
| Deposited By: | George Porter | ||||||
| Deposited On: | 22 Sep 2009 20:38 | ||||||
| Last Modified: | 26 Dec 2012 11:19 |
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