Mohammed, Omar F. and Kwon, Oh-Hoon and Othon, Christina M. and Zewail, Ahmed H. (2009) Charge Transfer Assisted by Collective Hydrogen-Bonding Dynamics. Angewandte Chemie International Edition, 48 (34). pp. 6251-6256. ISSN 1433-7851 http://resolver.caltech.edu/CaltechAUTHORS:20090908-083706313
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Bipolar disorder: Femtosecond spectroscopy of samples in protic and aprotic solvents of similar polarities reveals that charge-transfer processes are substantially facilitated by the formation of solute-solvent hydrogen-bond networks (see picture). This notion of molecular-specific interactions is not part of the continuum dielectric models of solvation and should be of significance to biological processes such as those of enzymes.
|Additional Information:||Copyright © 2009 WILEY. Received: May 1, 2009. Revised: June 18, 2009. Published online: July 14, 2009.|
|Subject Keywords:||charge transfer; femtochemistry; hydrogen-bonding dynamics; solvation dynamics; time-resolved fluorescence|
|Usage Policy:||No commercial reproduction, distribution, display or performance rights in this work are provided.|
|Deposited By:||George Porter|
|Deposited On:||15 Sep 2009 15:56|
|Last Modified:||26 Dec 2012 11:20|
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