Li, Jean and Stewart, Ian C. and Grubbs, Robert H. (2010) Synthesis and Structures of Fused N-Heterocylic Carbenes and Their Rhodium Complexes. Organometallics, 29 (17). pp. 3765-3768. ISSN 0276-7333 http://resolver.caltech.edu/CaltechAUTHORS:20100920-145414074
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Abstract
New procedures for the synthesis of N-heterocyclic carbenes with multiple fused rings have been developed utilizing a key ring-closing metathesis step. Rhodium complexes were obtained via the pentafluorophenyl carbene adducts. Solid-state structural behaviors of the new carbene ligands were analyzed via X-ray crystallography.
| Item Type: | Article | ||||||||||||
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| Additional Information: | © 2010 American Chemical Society. Received April 2, 2010. Publication Date (Web): August 5, 2010. The authors wish to thank the NIH (F32GM078734 and K99GM084302 to I.C.S. and 5RO1GM31332 to R.H.G.) for generous financial support. J.L. thanks the National Science Foundation for a Graduate Research Fellowship. This research was made with government support under and awarded by DoD, Air Force Office of Scientific Research, National Defense Science and Engineering Graduate (NDSEG) Fellowship, 32 CFR 168a. Dr.Michael W. Day and Lawrence M. Henling are thanked for crystallographic work, and Dr. David Vandervelde is thanked for NMR spectroscopy work. | ||||||||||||
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| Record Number: | CaltechAUTHORS:20100920-145414074 | ||||||||||||
| Persistent URL: | http://resolver.caltech.edu/CaltechAUTHORS:20100920-145414074 | ||||||||||||
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| Official Citation: | Synthesis and Structures of Fused N-Heterocylic Carbenes and Their Rhodium Complexes Jean Li, Ian C. Stewart, Robert H. Grubbs Organometallics 2010 29 (17), 3765-3768 | ||||||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||||||||
| ID Code: | 20053 | ||||||||||||
| Collection: | CaltechAUTHORS | ||||||||||||
| Deposited By: | Tony Diaz | ||||||||||||
| Deposited On: | 24 Sep 2010 19:38 | ||||||||||||
| Last Modified: | 26 Dec 2012 12:26 |
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