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Dielectric relaxation and intramolecular electron transfers

Sumi, H. and Marcus, R. A. (1986) Dielectric relaxation and intramolecular electron transfers. Journal of Chemical Physics, 84 (8). pp. 4272-4276. ISSN 0021-9606. http://resolver.caltech.edu/CaltechAUTHORS:SUMjcp86a

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Abstract

Intramolecular charge transfer are considered for the case that the motion of the system is on a single potential energy surface. The case where this motion occurred on two surfaces was considered elsewhere. The former is shown to be much preferable for studies of solvent dynamics. Several aspects of the relation between "constant charge" dielectric relaxation time of the polar solvent and the experimental decay time of emission from the polar excited state of the solute are discussed for hydrogen-bonded systems.


Item Type:Article
Additional Information:Copyright © 1986 American Institute of Physics (Received 29 July 1985; accepted 16 January 1986) The support of this research by a grant from the Ministry of Education of Japan (to H.S.) and from the National Science Foundation (to R.A.M.) is gratefully acknowledged.
Subject Keywords:ELECTRON TRANSFER; SOLVENTS; DIELECTRIC PROPERTIES; RELAXATION; CHEMICAL REACTIONS
Record Number:CaltechAUTHORS:SUMjcp86a
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:SUMjcp86a
Alternative URL:http://dx.doi.org/10.1063/1.450804
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:2138
Collection:CaltechAUTHORS
Deposited By: Archive Administrator
Deposited On:10 Mar 2006
Last Modified:26 Dec 2012 08:47

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