Sumi, H. and Marcus, R. A. (1986) Dielectric relaxation and intramolecular electron transfers. Journal of Chemical Physics, 84 (8). pp. 4272-4276. ISSN 0021-9606 http://resolver.caltech.edu/CaltechAUTHORS:SUMjcp86a
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Abstract
Intramolecular charge transfer are considered for the case that the motion of the system is on a single potential energy surface. The case where this motion occurred on two surfaces was considered elsewhere. The former is shown to be much preferable for studies of solvent dynamics. Several aspects of the relation between "constant charge" dielectric relaxation time of the polar solvent and the experimental decay time of emission from the polar excited state of the solute are discussed for hydrogen-bonded systems.
| Item Type: | Article |
|---|---|
| Additional Information: | Copyright © 1986 American Institute of Physics (Received 29 July 1985; accepted 16 January 1986) The support of this research by a grant from the Ministry of Education of Japan (to H.S.) and from the National Science Foundation (to R.A.M.) is gratefully acknowledged. |
| Subject Keywords: | ELECTRON TRANSFER; SOLVENTS; DIELECTRIC PROPERTIES; RELAXATION; CHEMICAL REACTIONS |
| Record Number: | CaltechAUTHORS:SUMjcp86a |
| Persistent URL: | http://resolver.caltech.edu/CaltechAUTHORS:SUMjcp86a |
| Alternative URL: | http://dx.doi.org/10.1063/1.450804 |
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. |
| ID Code: | 2138 |
| Collection: | CaltechAUTHORS |
| Deposited By: | Archive Administrator |
| Deposited On: | 10 Mar 2006 |
| Last Modified: | 26 Dec 2012 08:47 |
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