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Absolute infrared intensity measurements on nitrogen dioxide and dinitrogen tetroxide

Gutman, A. (1962) Absolute infrared intensity measurements on nitrogen dioxide and dinitrogen tetroxide. Journal of Quantitative Spectroscopy and Radiative Transfer, 2 (1). pp. 1-15. ISSN 0022-4073. http://resolver.caltech.edu/CaltechAUTHORS:20110111-134738438

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Abstract

The integrated intensities as a function of temperature have been measured for one NO_2 and for four N_2O_4 combination bands in the spectral region from 1 to 5µ. The temperature was varied from 50 to 100°C for the gas-phase studies and from 25 to 100°C for the liquid-phase experiments. In the spectral region from 5 to 15µ, integrated intensities at 25°C were measured for one NO_2 and for three N_2O_4 fundamental bands. Saturated vapors were used in all experiments; the optical depth was varied by using a series of spacers in a specially designed infrared absorption cell capable of handling both liquid and gas. Measured intensities for N_2O_4 combination bands in the liquid and gas phases were compared and found to differ by less than 16 per cent for three out of four combination bands studied; for the fourth band, the observed difference was about 50 per cent. Results for all of the combination bands investigated indicate that the integrated intensities vary approximately as l/T in the temperature range under consideration.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1016/0022-4073(62)90011-0DOIUNSPECIFIED
http://www.sciencedirect.com/science/article/B6TVR-46DFNFN-1X/2/c860044575cec90151a02d335bedcfeePublisherUNSPECIFIED
Additional Information:© 1961 Pergamon Press Ltd. Received 20 June 1961. Available online 31 July 2002. Supported by the U.S. Navy, Office of Naval Research, under Contract Nonr-220(03), NR 015401. For a more detailed description of the experimental studies, see the Ph.D. Thesis of A. Guttman, California Institute of Technology, Pasadena, 1962. The author is indebted to Dr. S. S. Penner for suggesting this investigation and for his helpful discussions and suggestions during the course of the work. Grateful appreciation is also extended to Dr. T. A. Jacobs for his assistance with the experimental work.
Group:Guggenheim Jet Propulsion Center
Funders:
Funding AgencyGrant Number
U.S. Navy UNSPECIFIED
Office of Naval Research (ONR)Nonr-220 (03), NR 015 401
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Guggenheim Jet Propulsion Center UNSPECIFIED
Record Number:CaltechAUTHORS:20110111-134738438
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20110111-134738438
Official Citation:A. Guttman, Absolute infrared intensity measurements on nitrogen dioxide and dinitrogen tetroxide, Journal of Quantitative Spectroscopy and Radiative Transfer, Volume 2, Issue 1, January-March 1962, Pages 1-15, ISSN 0022-4073, DOI: 10.1016/0022-4073(62)90011-0. (http://www.sciencedirect.com/science/article/B6TVR-46DFNFN-1X/2/c860044575cec90151a02d335bedcfee)
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:21709
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:14 Jan 2011 22:18
Last Modified:26 Dec 2012 12:50

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