Conley, Brian L. and Tenn, William J. and Young, Kenneth J.H. and Ganesh, Somesh K. and Meier, Steven K. and Ziatdinov, Vadim R. and Mironov, Oleg and Oxgaard, Jonas and Gonzales, Jason and Goddard, William A., III and Periana, Roy A. (2006) Design and study of homogeneous catalysts for the selective, low temperature oxidation of hydrocarbons. Journal of Molecular Catalysis A:Chemical , 251 (1-2). pp. 8-23. ISSN 1381-1169 http://resolver.caltech.edu/CaltechAUTHORS:20110225-091425462
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The direct, low temperature conversion of hydrocarbons to functionalized products using novel, single site catalysts could lead to technological advances that redefine the landscape of the current materials and energy industries. Natural gas continues to represent a vast source of untapped hydrocarbons around the globe that has the potential to replace or augment petroleum as the raw material for materials and energy. Its abundance has garnered much interest in the scientific community as groups have focused on the catalytic conversion of its major component, methane, to functionalized products. The key requirements is to design new catalysts for the oxidative functionalization of methane that operate at lower temperatures and that also meet the basic requirements of selectivity, rate, and lifetime that characterize useful catalysts. Recent advances in the field of hydrocarbon CH activation have shown the potential for transition metal based coordination catalysts to meet these requirements. Described herein are recent advances in designing catalysts based on the CH activation reaction that address the basic requirements for practical systems with emphasis on the issues that have prevented promising reported systems from becoming commercially viable.
|Additional Information:||© 2006 Elsevier B.V. Available online 30 March 2006.|
|Subject Keywords:||homogeneous catalyst; low temperature oxidation; hydrocarbon|
|Official Citation:||Brian L. Conley, William J. Tenn III, Kenneth J.H. Young, Somesh K. Ganesh, Steven K. Meier, Vadim R. Ziatdinov, Oleg Mironov, Jonas Oxgaard, Jason Gonzales, William A. Goddard III, Roy A. Periana, Design and study of homogeneous catalysts for the selective, low temperature oxidation of hydrocarbons, Journal of Molecular Catalysis A: Chemical, Volume 251, Issues 1-2, The 9th International Symposium Activation of Dioxygen and Homogeneous Catalytic Oxidation, The 9th International Symposium Activation of Dioxygen and Homogeneous Catalytic Oxidation, 17 May 2006, Pages 8-23, ISSN 1381-1169, DOI: 10.1016/j.molcata.2006.02.035. (http://www.sciencedirect.com/science/article/B6TGM-4JKRWJN-3/2/b413b146557c8f9b7e2168f0a0b78bc8)|
|Usage Policy:||No commercial reproduction, distribution, display or performance rights in this work are provided.|
|Deposited By:||Ruth Sustaita|
|Deposited On:||25 Feb 2011 21:44|
|Last Modified:||25 Feb 2011 21:44|
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