Liu, Xiang Y. and Lokare, Kapil S. and Ganesh, Somesh K. and Gonzales, Jason M. and Oxgaard, Jonas and Goddard, William A., III and Periana, Roy A. (2011) Rhodium complexes bearing tetradentate diamine-bis(phenolate) ligands. Dalton Transactions, 40 (1). pp. 301-304. ISSN 1477-9226 http://resolver.caltech.edu/CaltechAUTHORS:20110308-083347509
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Abstract
Using tetradentate, dianionic ligands, several new rhodium complexes have been prepared. Some of these diamine-bis(phenolate) compounds, are active for C–H activation of benzene. These complexes are air and thermally stable. All four complexes were characterized by X-ray diffraction.
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| Additional Information: | © 2011 The Royal Society of Chemistry. Received 11th August 2010, Accepted 20th September 2010. The authors thank Chevron Energy Technology Company, Center for Catalytic Hydrocarbon Functionalization, an Energy Frontier Research Center (DOE DE-SC000-1298) and Scripps Florida for financial Support. The facilities of the Materials and Process Simulation Center used for these studies were provided by DURIP-ARO and DURIP-ONR. The authors thank Muhammed Yousufuddin, Nam Nhat Ho, Irina Tsyba and Professor Bau for X-ray diffraction studies. The authors also thank Mu-Jeng Cheng, Robert J. Nielsen, and Richard J. Staples for helpful discussions. | ||||||||||
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| Record Number: | CaltechAUTHORS:20110308-083347509 | ||||||||||
| Persistent URL: | http://resolver.caltech.edu/CaltechAUTHORS:20110308-083347509 | ||||||||||
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| ID Code: | 22704 | ||||||||||
| Collection: | CaltechAUTHORS | ||||||||||
| Deposited By: | Tony Diaz | ||||||||||
| Deposited On: | 08 Mar 2011 17:49 | ||||||||||
| Last Modified: | 26 Dec 2012 13:00 |
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