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The series spectra of three-valence-electron atoms of phosphorus (PIII), sulphur (SIV), and chlorine (ClV)

Millikan, R. A. and Bowen, I. S. (1925) The series spectra of three-valence-electron atoms of phosphorus (PIII), sulphur (SIV), and chlorine (ClV). Physical Review, 25 (5). pp. 600-605. ISSN 0031-899X. http://resolver.caltech.edu/CaltechAUTHORS:MILpr25

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Abstract

Series spectra of three-valence-electron atoms of P, S and Cl.—By the methods of the preceding paper, 21 lines of PIII have been identified, 20 lines of SIV and 10 lines of ClV, including a pp′ group for each; also 10 term values of PIII have been determined and 10 term values of SIV, including the x level. Screening constants for one, two, and three valence electron systems are collected in a table for Na to Cl. The values increase regularly with the number of valence electrons and decrease with the atomic number, the difference decreasing as the atomic number increases.


Item Type:Article
Additional Information:©1925 The American Physical Society. Received 5 February 1925.
Record Number:CaltechAUTHORS:MILpr25
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:MILpr25
Alternative URL:http://dx.doi.org/10.1103/PhysRev.25.600
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:2311
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:25 Mar 2006
Last Modified:26 Dec 2012 08:48

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