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Trinuclear first row transition metal complexes of a hexapyridyl, trialkoxy 1,3,5-triarylbenzene ligand

Tsui, Emily Y. and Kanady, Jacob S. and Day, Michael W. and Agapie, Theodor (2011) Trinuclear first row transition metal complexes of a hexapyridyl, trialkoxy 1,3,5-triarylbenzene ligand. Chemical Communications, 47 (14). pp. 4189-4191. ISSN 1359-7345 http://resolver.caltech.edu/CaltechAUTHORS:20110420-090320294

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Abstract

Trinuclear complexes of Mn^(II), Fe^(II), Co^(II), Ni^(II), Cu^(II), and Zn^(II) were synthesized using a ligand architecture based upon a 1,3,5- triarylbenzene core decorated with six pyridines and three alkoxide moieties. Characterization via X-ray diffraction, NMR, and magnetism studies is discussed.


Item Type:Article
Additional Information:© 2011 The Royal Society of Chemistry. Received 16th December 2010, Accepted 14th February 2011. We thank Lawrence M. Henling for crystallographic assistance. We are grateful to Caltech, Chemistry Department Dow Fellowship (JSK), and NSF GRFP (EYT) for funding. The Bruker KAPPA APEXII X-ray diffractometer was purchased via an NSF CRIF:MU award to Caltech, CHE-0639094. SQUID data were collected at the MMRC of the Beckman Institute of the California Institute of Technology.
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Funding AgencyGrant Number
Caltech Chemistry Department Dow FellowshipUNSPECIFIED
NSF Graduate Research Fellowship Program (GRFP)UNSPECIFIED
NSF CHE-0639094
Record Number:CaltechAUTHORS:20110420-090320294
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20110420-090320294
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ID Code:23389
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:22 Apr 2011 17:05
Last Modified:26 Dec 2012 13:10

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