Endo, Koji and Grubbs, Robert H. (2011) Chelated Ruthenium Catalysts for Z-Selective Olefin Metathesis. Journal of the American Chemical Society, 133 (22). pp. 8525-8527. ISSN 0002-7863 http://resolver.caltech.edu/CaltechAUTHORS:20110627-091657365
![[img]](http://authors.library.caltech.edu/style/images/fileicons/application_pdf.png)
|
PDF
- Published Version
See Usage Policy. 977Kb | |
|
PDF
- Supplemental Material
See Usage Policy. 1405Kb | |
![[img]](http://authors.library.caltech.edu/style/images/fileicons/other.png) |
Crystallographic Info File (CIF)
- Supplemental Material
See Usage Policy. 31Kb | |
|
Crystallographic Info File (CIF)
- Supplemental Material
See Usage Policy. 21Kb | |
|
Crystallographic Info File (CIF)
- Supplemental Material
See Usage Policy. 22Kb |
Use this Persistent URL to link to this item: http://resolver.caltech.edu/CaltechAUTHORS:20110627-091657365
Abstract
We report the development of ruthenium-based metathesis catalysts with chelating N-heterocyclic carbene (NHC) ligands that catalyze highly Z-selective olefin metathesis. A very simple and convenient procedure for the synthesis of such catalysts has been developed. Intramolecular C–H bond activation of the NHC ligand, promoted by anion ligand substitution, forms the appropriate chelate for stereocontrolled olefin metathesis.
| Item Type: | Article | ||||||||
|---|---|---|---|---|---|---|---|---|---|
| Additional Information: | © 2011 American Chemical Society. Received: March 28, 2011. Published in issue June 08, 2011. Publication Date (Web): May 12, 2011. We thank Mr. B. K. Keitz, Mr.M. B. Herbert, and Dr. P. Teo for helpful discussions and suggestions for this work, Materia, Inc. for the generous donation of catalysts, and Dr. M. W. Day and Mr. L. M. Henling for X-ray crystallography. The Bruker KAPPA APEXII X-ray diffractometer was purchased via an NSF CRIF:MU award to the California Institute of Technology, CHE-0639094. This work was financially supported by National Institutes of Health (NIH 5R01GM031332-27) and Mitsui Chemicals, Inc. | ||||||||
| Funders: |
| ||||||||
| Record Number: | CaltechAUTHORS:20110627-091657365 | ||||||||
| Persistent URL: | http://resolver.caltech.edu/CaltechAUTHORS:20110627-091657365 | ||||||||
| Related URLs: | |||||||||
| Official Citation: | Chelated Ruthenium Catalysts for Z-Selective Olefin Metathesis Koji Endo, Robert H. Grubbs Journal of the American Chemical Society 2011 133 (22), 8525-8527 | ||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||||
| ID Code: | 24214 | ||||||||
| Collection: | CaltechAUTHORS | ||||||||
| Deposited By: | Ruth Sustaita | ||||||||
| Deposited On: | 27 Jun 2011 16:43 | ||||||||
| Last Modified: | 26 Dec 2012 13:20 |
Repository Staff Only: item control page
