Keitz, Benjamin K. and Endo, Koji and Herbert, Myles B. and Grubbs, Robert H. (2011) Z-Selective Homodimerization of Terminal Olefins with a Ruthenium Metathesis Catalyst. Journal of the American Chemical Society, 133 (25). pp. 9686-9688. ISSN 0002-7863 http://resolver.caltech.edu/CaltechAUTHORS:20110802-144731917
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The cross-metathesis of terminal olefins using a novel ruthenium catalyst results in excellent selectivity for the Z-olefin homodimer. The reaction was found to tolerate a large number of functional groups, solvents, and temperatures while maintaining excellent Z-selectivity, even at high reaction conversions.
|Additional Information:||© 2011 American Chemical Society. Received: April 15, 2011. Published: June 08, 2011. Publication Date (Web): June 8, 2011. This work was financially supported by the NIH (NIH 5R01GM031332-27), the NSF (CHE-1048404), Mitsui Chemicals, Inc. (K.E.), and the NDSEG (fellowship to B.K.K.). Instrumentation facilities at which this work was carried out were supported by NIH RR027690. Materia, Inc. is thanked for its donation of metathesis catalysts.|
|Official Citation:||Z-Selective Homodimerization of Terminal Olefins with a Ruthenium Metathesis Catalyst Benjamin K. Keitz, Koji Endo, Myles B. Herbert, Robert H. Grubbs Journal of the American Chemical Society 2011 133 (25), 9686-9688|
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|Deposited By:||Ruth Sustaita|
|Deposited On:||02 Aug 2011 22:43|
|Last Modified:||26 Dec 2012 13:26|
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