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Synthesis of neutral nickel catalysts for ethylene polymerization – the influence of ligand size on catalyst stability

Connor, Eric F. and Younkin, Todd R. and Henderson, Jason I. and Waltman, Andrew W. and Grubbs, Robert H. (2003) Synthesis of neutral nickel catalysts for ethylene polymerization – the influence of ligand size on catalyst stability. Chemical Communications, 2003 (18). pp. 2272-2273. ISSN 1359-7345. http://resolver.caltech.edu/CaltechAUTHORS:20111011-091857045

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Abstract

A facile synthesis of nickel salicylaldimine complexes with labile dissociating ligands is described. In addition to producing highly active ethylene polymerization catalysts, important insights into the effect of ligand size on catalyst stability and information on the mechanism of polymerization are provided.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1039/b306701gDOIUNSPECIFIED
http://pubs.rsc.org/en/Content/ArticleLanding/2003/CC/b306701gPublisherUNSPECIFIED
Additional Information:© 2003 The Royal Society of Chemistry. Received (in West Lafayette, IN, USA) 12th June 2003, Accepted 30th July 2003. First published as an Advance Article on the web 15th August 2003. Support was provided by the National Institute for Standards and Technology (ATP program) and the Cryovac Division of the Sealed Air Corporation. Drs Michael Day and Lawrence Henling performed the crystallographic analysis.
Funders:
Funding AgencyGrant Number
National Institute for Standards and Technology (ATP program)UNSPECIFIED
Sealed Air Corporation Cryovac Division UNSPECIFIED
Record Number:CaltechAUTHORS:20111011-091857045
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20111011-091857045
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:27154
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:11 Oct 2011 21:48
Last Modified:26 Dec 2012 14:15

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