Bendix, Jesper and Gray, Harry B. and Golubkov, Galina and Gross, Zeev (2000) High-field (high-frequency) EPR spectroscopy and structural characterization of a novel manganese(III) corrole. Chemical Communications, 2000 (19). pp. 1957-1958. ISSN 1359-7345 http://resolver.caltech.edu/CaltechAUTHORS:20111123-083709397
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The X-ray structure, magnetic susceptibility, and high-field (high-frequency) EPR spectrum of manganese 5,10,15-tris(pentafluorophenyl) corrole unambiguously establish that the complex contains an isolated, slightly rhombic, manganese(III) center.
|Additional Information:||© 2000 The Royal Society of Chemistry. Received 02 Aug 2000, Accepted 30 Aug 2000. First published on the web 21 Sep 2000. We thank Dr M. W. Day (Beckman Institute) for assistance with the crystal structure determination and Ms S. Mossin (University of Copenhagen) and Dr A.-L. Barra (CNRS, Grenoble) for recording the HF-EPR spectra. This research was supported by the Fund for the Promotion of Research at the Technion (Z. G.), the National Science Foundation (H. B. G.), and grant # 9800549 from the Danish Natural Science Research Council (J. B.).|
|Official Citation:||High-field (high-frequency) EPR spectroscopy and structural characterization of a novel manganese(III) corrole Jesper Bendix, Harry B. Gray, Galina Golubkov and Zeev Gross Chem. Commun., 2000, 1957-1958 DOI: 10.1039/B006299P|
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|Deposited By:||Ruth Sustaita|
|Deposited On:||23 Nov 2011 17:27|
|Last Modified:||26 Dec 2012 14:27|
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