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Buchner and Beyond: Arene Cyclopropanation as Applied to Natural Product Total Synthesis

Reisman, Sarah E. and Nani, Roger R. and Levin, Sergiy (2011) Buchner and Beyond: Arene Cyclopropanation as Applied to Natural Product Total Synthesis. Synlett, 2011 (17). pp. 2437-2442. ISSN 0936-5214 http://resolver.caltech.edu/CaltechAUTHORS:20111212-082239823

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Abstract

Buchner and Curtius first reported the cyclopropanation of arenes in 1885. Since the initial discovery, the Buchner reaction has been the subject of significant research by both physical and synthetic organic chemists. Described herein is a brief overview of the Buchner reaction and related arene cyclopropanation processes, with an emphasis on their application to natural product total synthesis.


Item Type:Article
Additional Information:© 2011 Georg Thieme Verlag Stuttgart. Received 25 April 2011. Advanced online publication: 06.10.2011. Financial support from the California Institute of Technology is gratefully acknowledged.
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Subject Keywords:Buchner; cyclopropanation; diazo; norcaradiene; cycloheptatriene; total synthesis
Record Number:CaltechAUTHORS:20111212-082239823
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20111212-082239823
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Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:28411
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:13 Dec 2011 16:49
Last Modified:11 Oct 2012 18:58

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