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A terminal molybdenum carbide prepared by methylidyne deprotonation

Peters, Jonas C. and Odom, Aaron L. and Cummins, Christopher C. (1997) A terminal molybdenum carbide prepared by methylidyne deprotonation. Chemical Communications, 1997 (20). pp. 1995-1996. ISSN 1359-7345. http://resolver.caltech.edu/CaltechAUTHORS:20120125-111723380

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Abstract

The carbide anion [CMo{N(R)Ar}_3]– [R = C(CD_3)_2CH_3, Ar = C_6H_3Me_2-3,5], is obtained by deprotonation of the corresponding methylidyne compound, [HCMo{N(R)Ar}_3], and is characterized by X-ray diffraction as its {K(benzo-15-crown-5)_2}+ salt, thereby providing precedent for the carbon atom as a terminal substituent in transition-metal chemistry.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1039/A704251E DOIUNSPECIFIED
http://pubs.rsc.org/en/Content/ArticleLanding/1997/CC/a704251ePublisherUNSPECIFIED
Additional Information:© 1997 Royal Society of Chemistry. Received in Bloomington, IN, USA, 17th June 1997; 7/04251E.
Record Number:CaltechAUTHORS:20120125-111723380
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20120125-111723380
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:28959
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:13 Apr 2012 21:55
Last Modified:26 Dec 2012 14:44

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