Peters, Jonas C. and Odom, Aaron L. and Cummins, Christopher C. (1997) A terminal molybdenum carbide prepared by methylidyne deprotonation. Chemical Communications, 1997 (20). pp. 1995-1996. ISSN 1359-7345 http://resolver.caltech.edu/CaltechAUTHORS:20120125-111723380
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Abstract
The carbide anion [CMo{N(R)Ar}_3]– [R = C(CD_3)_2CH_3, Ar = C_6H_3Me_2-3,5], is obtained by deprotonation of the corresponding methylidyne compound, [HCMo{N(R)Ar}_3], and is characterized by X-ray diffraction as its {K(benzo-15-crown-5)_2}+ salt, thereby providing precedent for the carbon atom as a terminal substituent in transition-metal chemistry.
| Item Type: | Article |
|---|---|
| Additional Information: | © 1997 Royal Society of Chemistry. Received in Bloomington, IN, USA, 17th June 1997; 7/04251E. |
| Record Number: | CaltechAUTHORS:20120125-111723380 |
| Persistent URL: | http://resolver.caltech.edu/CaltechAUTHORS:20120125-111723380 |
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| ID Code: | 28959 |
| Collection: | CaltechAUTHORS |
| Deposited By: | Tony Diaz |
| Deposited On: | 13 Apr 2012 21:55 |
| Last Modified: | 26 Dec 2012 14:44 |
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