Moore, Teresa A. and Okumura, Mitchio and Minton, Timothy K. (1997) Photodissociation of Cl_2O at 248 and 308 nm. Journal of Chemical Physics, 107 (8). pp. 3337-3338. ISSN 0021-9606 http://resolver.caltech.edu/CaltechAUTHORS:20120130-084809523
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Abstract
Molecular beam studies of Cl_2O photolysis at 248 and 308 nm have been repeated and the analysis refined. At 248 nm, three distinct dissociation pathways that led to Cl+ClO products were resolved. At 308 nm, the angular distribution was slightly more isotropic than previously reported, leaving open the possibility that Cl_2O excited at 308 nm lives longer than a rotational period.
| Item Type: | Article | ||||||
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| Additional Information: | © 1997 American Institute of Physics. Received 14 March 1997; accepted 19 May 1997. We acknowledge support of NASA Grant No. NAGW-3893, Montana Space Grant Consortium Federal Grant No. NGT-40041-2, and assistance from C. M. Nelson and J. W. Seale. | ||||||
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| Subject Keywords: | chlorine compounds, photodissociation, photolysis, time of flight spectra | ||||||
| Classification Code: | PACS: 33.80.Gj; 82.50.Bc; 82.50.Hp; 07.57.-c; 07.60.-j | ||||||
| Record Number: | CaltechAUTHORS:20120130-084809523 | ||||||
| Persistent URL: | http://resolver.caltech.edu/CaltechAUTHORS:20120130-084809523 | ||||||
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| Official Citation: | Photodissociation of Cl2O at 248 and 308 nm Teresa A. Moore, Mitchio Okumura, and Timothy K. Minton J. Chem. Phys. 107, 3337 (1997); doi:10.1063/1.474706 | ||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||
| ID Code: | 29014 | ||||||
| Collection: | CaltechAUTHORS | ||||||
| Deposited By: | Ruth Sustaita | ||||||
| Deposited On: | 30 Jan 2012 17:35 | ||||||
| Last Modified: | 26 Dec 2012 14:45 |
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