Moore, Teresa A. and Okumura, Mitchio and Minton, Timothy K. (1997) Photodissociation of Cl_2O at 248 and 308 nm. Journal of Chemical Physics, 107 (8). pp. 3337-3338. ISSN 0021-9606 http://resolver.caltech.edu/CaltechAUTHORS:20120130-084809523
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Molecular beam studies of Cl_2O photolysis at 248 and 308 nm have been repeated and the analysis refined. At 248 nm, three distinct dissociation pathways that led to Cl+ClO products were resolved. At 308 nm, the angular distribution was slightly more isotropic than previously reported, leaving open the possibility that Cl_2O excited at 308 nm lives longer than a rotational period.
|Additional Information:||© 1997 American Institute of Physics. Received 14 March 1997; accepted 19 May 1997. We acknowledge support of NASA Grant No. NAGW-3893, Montana Space Grant Consortium Federal Grant No. NGT-40041-2, and assistance from C. M. Nelson and J. W. Seale.|
|Subject Keywords:||chlorine compounds, photodissociation, photolysis, time of flight spectra|
|Classification Code:||PACS: 33.80.Gj; 82.50.Bc; 82.50.Hp; 07.57.-c; 07.60.-j|
|Official Citation:||Photodissociation of Cl2O at 248 and 308 nm Teresa A. Moore, Mitchio Okumura, and Timothy K. Minton J. Chem. Phys. 107, 3337 (1997); doi:10.1063/1.474706|
|Usage Policy:||No commercial reproduction, distribution, display or performance rights in this work are provided.|
|Deposited By:||Ruth Sustaita|
|Deposited On:||30 Jan 2012 17:35|
|Last Modified:||26 Dec 2012 14:45|
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