Iluc, Vlad M. and Fedorov, Alexey and Grubbs, Robert H. (2011) H/D Exchange Processes Catalyzed by an Iridium-Pincer Complex. Organometallics, 31 (1). pp. 39-41. ISSN 0276-7333 http://resolver.caltech.edu/CaltechAUTHORS:20120210-151229549
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Abstract
A PNP-pincer iridium dihydride performs the H/D exchange between aromatic substrates and tertiary hydrosilanes and D_(2)O or C_(6)D_(6). Complete incorporation of deuterium into sterically accessible C_(ar)–H and Si–H bonds was observed at a moderate temperature of 80 °C.
| Item Type: | Article | ||||||
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| Additional Information: | © 2011 American Chemical Society. Received: October 28, 2011; Published: December 15, 2011. Generous financial support of this research was provided by BP (MC2 initiative). A.F. thanks the Swiss National Science Foundation for a postdoctoral fellowship. | ||||||
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| Record Number: | CaltechAUTHORS:20120210-151229549 | ||||||
| Persistent URL: | http://resolver.caltech.edu/CaltechAUTHORS:20120210-151229549 | ||||||
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| Official Citation: | H/D Exchange Processes Catalyzed by an Iridium-Pincer Complex Vlad M. Iluc, Alexey Fedorov, and Robert H. Grubbs Organometallics 2012 31 (1), 39-41 | ||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||
| ID Code: | 29247 | ||||||
| Collection: | CaltechAUTHORS | ||||||
| Deposited By: | Jason Perez | ||||||
| Deposited On: | 10 Feb 2012 23:56 | ||||||
| Last Modified: | 26 Dec 2012 14:49 |
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