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Synthesis and crystal structure of the first 6a-thiathiophthen metal complex [Mo(CO)_5PPh_(2]2)(µ-C_5H_2S_3)

Yih, Kuang-Hway and Lin, Ying-Chih and Lee, Gene-Hsiang and Wang, Yu (1995) Synthesis and crystal structure of the first 6a-thiathiophthen metal complex [Mo(CO)_5PPh_(2]2)(µ-C_5H_2S_3). Journal of the Chemical Society. Chemical Communications, 1995 (2). pp. 223-224. ISSN 0022-4936. http://resolver.caltech.edu/CaltechAUTHORS:20120223-110545297

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Abstract

The first 6a-thiathiophthen metal complex was prepared by treating M(CO_)5[PPh_2CS_2CH_2C≡CH] with a catalytic amount of secondary amine or tertiary amine; the structure of the 6a-thiathiophthen molybdenum complex is confirmed by an X-ray diffraction analysis.


Item Type:Article
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http://dx.doi.org/10.1039/c39950000223 DOIUNSPECIFIED
http://pubs.rsc.org/en/Content/ArticleLanding/1995/C3/c39950000223PublisherUNSPECIFIED
Additional Information:© 1995 Royal Society of Chemistry. Received, 2nd November 1994. We thank the National Science Council of Taiwan, the Republic of China for support.
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Funding AgencyGrant Number
National Science Council of TaiwanUNSPECIFIED
Record Number:CaltechAUTHORS:20120223-110545297
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20120223-110545297
Official Citation:Synthesis and crystal structure of the first 6a-thiathiophthen metal complex [Mo(CO)5PPh2]2(µ-C5H2S3) Kuang-Hway Yih, Ying-Chih Lin, Gene-Hsiang Lee and Yu Wang J. Chem. Soc., Chem. Commun., 1995, 223-224 DOI: 10.1039/C39950000223
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:29439
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:23 Feb 2012 19:25
Last Modified:26 Dec 2012 14:52

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