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Synthesis and First Hyperpolarizabilities of Acceptor-substituted β-apo-8’-Carotenal Derived Compounds

Gilmour, Sandra and Marder, Seth R. and Tiemann, Bruce G. and Cheng, Lap-Tak (1993) Synthesis and First Hyperpolarizabilities of Acceptor-substituted β-apo-8’-Carotenal Derived Compounds. Journal of the Chemical Society. Chemical Communications (5). pp. 432-433. ISSN 0022-4936. http://resolver.caltech.edu/CaltechAUTHORS:20120307-101154560

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Abstract

The synthesis and second-order nonlinear optical properties of acceptor-substituted biologically derived β-apo-8′-carotenal compounds are reported; electric field-induced second harmonic generation (EFISH) measurements give values of β(0) which are 2–6 times greater than for 4-N,N-dimethylamino-4′-nitrostilbene (DANS).


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1039/C39930000432 DOIUNSPECIFIED
http://pubs.rsc.org/en/content/articlelanding/1993/c3/c39930000432PublisherUNSPECIFIED
Additional Information:© 1994 Royal Society of Chemistry. Received, 18th November 1992; Com. 2106147C. The work in this paper was performed, in part, by the Center for Space Microelectronics Technology, Jet Propulsion Laboratory, California Institute of Technology and was sponsored by the Strategic Defense Initiative Organization, Innovative Science and Technology Office and The Defense Advanced Research Projects Agency through grant no.91-NC-146 administered by the Air Force Office of Scientific Research through agreements with the National Aeronautics and Space Administration (NASA). Support from the National Science Foundation (Grant CHE-9106689) is also gratefully acknowledged. S. G. thanks the National Research Council (NRC) and NASA for an NRC Resident Research Associateship at the Jet Propulsion Laboratory. We thank Brian Pierce and Joseph Perry for helpful discussions.
Funders:
Funding AgencyGrant Number
Strategic Defense Initiative, Innovative Science and Technology OfficeUNSPECIFIED
Defense Advanced Research Projects Agency 91-NC-146
AFOSR NASAUNSPECIFIED
NSFCHE-9106689
National Research Council (NRC)UNSPECIFIED
NASA for an NRC Resident Research Associated at JPLUNSPECIFIED
Record Number:CaltechAUTHORS:20120307-101154560
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20120307-101154560
Official Citation:Synthesis and first hyperpolarizabilities of acceptor-substituted β-apo-8′-carotenal derived compounds Sandra Gilmour, Seth R. Marder, Bruce G. Tiemann and Lap-Tak Cheng J. Chem. Soc., Chem. Commun., 1993, 432-433 DOI: 10.1039/C39930000432
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:29615
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:07 Mar 2012 19:22
Last Modified:26 Dec 2012 14:55

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