Wan, Kam-to and Davis, Mark E. (1993) Asymmetric Hydrogenation in Water by a Rhodium Complex of Sulfonated 2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl (binap). Journal of the Chemical Society. Chemical Communications (16). pp. 1262-1264. ISSN 0022-4936 http://resolver.caltech.edu/CaltechAUTHORS:20120308-070629885
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The synthesis of sulfonated 2,2′-bis(diphenylphosphino)-1,1′-binaphthyl (binap) is reported; a rhodium complex of this ligand is the first to perform asymmetric hydrogenation in neat water with optical yields as high as those obtained in nonaqueous solvent.
|Additional Information:||© 1993 Royal Society of Chemistry. Received, 7th April 1993; Com. 3/02021E. Support for this work was provided by the NSF Alan T. Waterman Award to M. E. D. We thank Professor John Bercaw for helpful discussions|
|Official Citation:||Asymmetric hydrogenation in water by a rhodium complex of sulfonated 2,2′bis(diphenylphosphino)-1,1′-binaphthyl (binap) Kam-to Wan and Mark E. Davis J. Chem. Soc., Chem. Commun., 1993, 1262-1264 DOI: 10.1039/C39930001262|
|Usage Policy:||No commercial reproduction, distribution, display or performance rights in this work are provided.|
|Deposited By:||Ruth Sustaita|
|Deposited On:||12 Mar 2012 21:11|
|Last Modified:||26 Dec 2012 14:55|
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