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Asymmetric Hydrogenation in Water by a Rhodium Complex of Sulfonated 2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl (binap)

Wan, Kam-to and Davis, Mark E. (1993) Asymmetric Hydrogenation in Water by a Rhodium Complex of Sulfonated 2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl (binap). Journal of the Chemical Society. Chemical Communications (16). pp. 1262-1264. ISSN 0022-4936. http://resolver.caltech.edu/CaltechAUTHORS:20120308-070629885

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Abstract

The synthesis of sulfonated 2,2′-bis(diphenylphosphino)-1,1′-binaphthyl (binap) is reported; a rhodium complex of this ligand is the first to perform asymmetric hydrogenation in neat water with optical yields as high as those obtained in nonaqueous solvent.


Item Type:Article
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URLURL TypeDescription
http://dx.doi.org/10.1039/c39930001262DOIUNSPECIFIED
http://pubs.rsc.org/en/Content/ArticleLanding/1993/C3/c39930001262PublisherUNSPECIFIED
Additional Information:© 1993 Royal Society of Chemistry. Received, 7th April 1993; Com. 3/02021E. Support for this work was provided by the NSF Alan T. Waterman Award to M. E. D. We thank Professor John Bercaw for helpful discussions
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Funding AgencyGrant Number
NSF Alan T. Waterman AwardUNSPECIFIED
Record Number:CaltechAUTHORS:20120308-070629885
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20120308-070629885
Official Citation:Asymmetric hydrogenation in water by a rhodium complex of sulfonated 2,2′bis(diphenylphosphino)-1,1′-binaphthyl (binap) Kam-to Wan and Mark E. Davis J. Chem. Soc., Chem. Commun., 1993, 1262-1264 DOI: 10.1039/C39930001262
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:29638
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:12 Mar 2012 21:11
Last Modified:26 Dec 2012 14:55

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