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The First Molecular Electronic Hyperpolarizabilities of Highly Polarizable Organic Molecules: 2,6-Di-tert-butylindoanilines

Marder, Seth R. and Cheng, Lap-Tak and Tiemann, Bruce G. (1992) The First Molecular Electronic Hyperpolarizabilities of Highly Polarizable Organic Molecules: 2,6-Di-tert-butylindoanilines. Journal of the Chemical Society. Chemical Communications (9). pp. 672-674. ISSN 0022-4936. http://resolver.caltech.edu/CaltechAUTHORS:20120330-072052875

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Abstract

The first molecular hyperpolarizabilities (β) of a series of 2,6-di-tert-butylindoanilines, measured by electric-field-induced second harmonic generation are somewhat more sensitive to donor strength than was found for analogously substituted nitrostilbenes, and dimethylindoaniline has a β roughly twice that of its 2,6 di-tert-butylated analogue, measured in chloroform; solvatochromic measurements on the former compound suggest that this decrease in hyperpolarizability is consistent with a bound-solvent effect.


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http://dx.doi.org/10.1039/c39920000672DOIUNSPECIFIED
http://pubs.rsc.org/en/Content/ArticleLanding/1992/C3/c39920000672PublisherUNSPECIFIED
Additional Information:© 1992 Royal Society of Chemistry. Received, 3rd December 1991; Com. I/06124K. Research through agreements with the National Aeronautics and Space Administration (NASA).
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Record Number:CaltechAUTHORS:20120330-072052875
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20120330-072052875
Official Citation:The first molecular electronic hyperpolarizabilities of highly polarizable organic molecules: 2,6-di-tert-butylindoanilines Seth R. Marder, Lap-Tak Cheng and Bruce G. Tiemann J. Chem. Soc., Chem. Commun., 1992, 672-674 DOI: 10.1039/C39920000672
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:29905
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:30 Mar 2012 14:56
Last Modified:26 Dec 2012 15:00

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