Direct observation of the picosecond dynamics of I_2-Ar fragmentation

Breen, J. J. and Willberg, D. M. and Gutmann, M. and Zewail, A. H. (1990) Direct observation of the picosecond dynamics of I_2-Ar fragmentation. Journal of Chemical Physics, 93 (12). pp. 9180-9184. ISSN 0021-9606 http://resolver.caltech.edu/CaltechAUTHORS:20120424-142558756

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Abstract

Picosecond real‐time observations of the dynamics of I_2–Ar fragmentation are reported. The state‐to‐state rates, k(ν^i,,ν^f,), are directly measured and related to the homogeneous broadening of the initial state, and to product state distributions in the exit channel. Comparisons with different theories of vibrational (and electronic) predissociation are made.

Item Type:

Article

Additional Information:

Funders:

Funding Agency	Grant Number
NSF	UNSPECIFIED

Subject Keywords:

IODINE COMPLEXES, ARGON COMPLEXES, MOLECULAR CLUSTERS, DISSOCIATION, PREDISSOCIATION, FRAGMENTATION, VAN DER WAALS BINDING, PS RANGE

Classification Code:

PACS: 33.15.Hp, 36.40.-c, 33.80.Gj

Record Number:

CaltechAUTHORS:20120424-142558756

Persistent URL:

http://resolver.caltech.edu/CaltechAUTHORS:20120424-142558756

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Official Citation:

Direct observation of the picosecond dynamics of I2–Ar fragmentation J. J. Breen, D. M. Willberg, M. Gutmann, and A. H. Zewail J. Chem. Phys. 93, 9180 (1990); http://dx.doi.org/10.1063/1.459207

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ID Code:

30295

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CaltechAUTHORS

Deposited By:

Ruth Sustaita

Deposited On:

24 Apr 2012 21:52

Last Modified:

26 Dec 2012 15:07

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