CaltechAUTHORS
  A Caltech Library Service

Direct observation of the picosecond dynamics of I_2-Ar fragmentation

Breen, J. J. and Willberg, D. M. and Gutmann, M. and Zewail, A. H. (1990) Direct observation of the picosecond dynamics of I_2-Ar fragmentation. Journal of Chemical Physics, 93 (12). pp. 9180-9184. ISSN 0021-9606. http://resolver.caltech.edu/CaltechAUTHORS:20120424-142558756

[img]
Preview
PDF - Published Version
See Usage Policy.

347Kb

Use this Persistent URL to link to this item: http://resolver.caltech.edu/CaltechAUTHORS:20120424-142558756

Abstract

Picosecond real‐time observations of the dynamics of I_2–Ar fragmentation are reported. The state‐to‐state rates, k(ν^i,,ν^f,), are directly measured and related to the homogeneous broadening of the initial state, and to product state distributions in the exit channel. Comparisons with different theories of vibrational (and electronic) predissociation are made.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1063/1.459207DOIUNSPECIFIED
http://jcp.aip.org/resource/1/jcpsa6/v93/i12/p9180_s1PublisherUNSPECIFIED
Additional Information:© 1990 American Institute of Physics. Received 27 August 1990; accepted 3 October 1990. This work was supported by the National Science Foundation.
Funders:
Funding AgencyGrant Number
NSFUNSPECIFIED
Subject Keywords:IODINE COMPLEXES, ARGON COMPLEXES, MOLECULAR CLUSTERS, DISSOCIATION, PREDISSOCIATION, FRAGMENTATION, VAN DER WAALS BINDING, PS RANGE
Classification Code:PACS: 33.15.Hp, 36.40.-c, 33.80.Gj
Record Number:CaltechAUTHORS:20120424-142558756
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20120424-142558756
Official Citation:Direct observation of the picosecond dynamics of I2–Ar fragmentation J. J. Breen, D. M. Willberg, M. Gutmann, and A. H. Zewail J. Chem. Phys. 93, 9180 (1990); http://dx.doi.org/10.1063/1.459207
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:30295
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:24 Apr 2012 21:52
Last Modified:26 Dec 2012 15:07

Repository Staff Only: item control page