Bercaw, John E. and Burger, Barbara J. and Green, Malcolm L. H. and Santarsiero, Bernard D. and Sella, Andrea and Trimmer, Mark S. and Wong, Luet-Lok (1989) A new mechanism for exchange processes observed in the compounds [M(η-C_5H_5)_2(exo-η-RCH = CH_2)H], M = Nb and Ta. Journal of the Chemical Society. Chemical Communications, 1989 (11). pp. 734-736. ISSN 0022-4936 http://resolver.caltech.edu/CaltechAUTHORS:20120510-132916331
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Abstract
Dynamic n.m.r. studies of the exchange processes in the complexes [M(η-C_5H_5)(exo-η-RCH=CH_2)H], M = Nb, Ta, lead to the proposal of a new mechanism involving intermediates with agostic bonding.
| Item Type: | Article | ||||||
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| Additional Information: | © 1989 Royal Society of Chemistry. Received, 20th December 1988; Com. 8/04965C. We thank NATO (research grant 287-84) for support, and the Gas Research Institute for partial support, of this work. We thank D. O'Hare, C. M. Dobson, and S. J. Heyes for helpful discussion. | ||||||
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| Record Number: | CaltechAUTHORS:20120510-132916331 | ||||||
| Persistent URL: | http://resolver.caltech.edu/CaltechAUTHORS:20120510-132916331 | ||||||
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| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||
| ID Code: | 31418 | ||||||
| Collection: | CaltechAUTHORS | ||||||
| Deposited By: | Tony Diaz | ||||||
| Deposited On: | 10 May 2012 21:26 | ||||||
| Last Modified: | 26 Dec 2012 15:11 |
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