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A new mechanism for exchange processes observed in the compounds [M(η-C_5H_5)_2(exo-η-RCH = CH_2)H], M = Nb and Ta

Bercaw, John E. and Burger, Barbara J. and Green, Malcolm L. H. and Santarsiero, Bernard D. and Sella, Andrea and Trimmer, Mark S. and Wong, Luet-Lok (1989) A new mechanism for exchange processes observed in the compounds [M(η-C_5H_5)_2(exo-η-RCH = CH_2)H], M = Nb and Ta. Journal of the Chemical Society. Chemical Communications, 1989 (11). pp. 734-736. ISSN 0022-4936. http://resolver.caltech.edu/CaltechAUTHORS:20120510-132916331

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Abstract

Dynamic n.m.r. studies of the exchange processes in the complexes [M(η-C_5H_5)(exo-η-RCH=CH_2)H], M = Nb, Ta, lead to the proposal of a new mechanism involving intermediates with agostic bonding.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1039/c39890000734 DOIUNSPECIFIED
http://pubs.rsc.org/en/Content/ArticleLanding/1989/C3/c39890000734PublisherUNSPECIFIED
Additional Information:© 1989 Royal Society of Chemistry. Received, 20th December 1988; Com. 8/04965C. We thank NATO (research grant 287-84) for support, and the Gas Research Institute for partial support, of this work. We thank D. O'Hare, C. M. Dobson, and S. J. Heyes for helpful discussion.
Funders:
Funding AgencyGrant Number
NATO287-84
Gas Research Institute UNSPECIFIED
Record Number:CaltechAUTHORS:20120510-132916331
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20120510-132916331
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:31418
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:10 May 2012 21:26
Last Modified:26 Dec 2012 15:11

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