Parkin, Gerard and Bercaw, John E. (1989) Direct protonation of the W–H bonds of Bis(pentamethylcyclopentadienyl)tungsten dihydride. Journal of the Chemical Society. Chemical Communications, 1989 (4). pp. 255-257. ISSN 0022-4936 http://resolver.caltech.edu/CaltechAUTHORS:20120517-111723864
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Protonation of (C_5Me_5)_2 WH_2 to give [(C_5Me_5)_2WH_3]+ is proposed to occur by attack at both W–H bonds rather than by direct attack at the d^2 metal centre.
|Additional Information:||© 1989 Royal Society of Chemistry. Received, 7th June 1988; Com. 8/02277A. We thank Professor Bruce Bursten for helpful discussions. This work was supported by the National Science Foundation (Grant No. CHE-8600875) and by Shell Companies Foundation, which are gratefully acknowledged. G. P. acknowledges support through a NATO Postdoctoral Fellowship administered through the S.E.R.C. (U.K.).|
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|Deposited By:||Tony Diaz|
|Deposited On:||22 May 2012 17:22|
|Last Modified:||26 Dec 2012 15:13|
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