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Rotationally resolved photoelectron angular distributions in resonance enhanced multiphoton ionization of NO

Rudolph, H. and McKoy, V. (1989) Rotationally resolved photoelectron angular distributions in resonance enhanced multiphoton ionization of NO. Journal of Chemical Physics, 91 (4). pp. 2235-2238. ISSN 0021-9606. http://resolver.caltech.edu/CaltechAUTHORS:20120530-144040127

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Abstract

We report calculated ionic rotational branching ratios and associated photoelectron angular distributions for (1+1′) resonance enhanced multiphoton ionization (REMPI) via the R_(21)(20.5), P_(21)+Q_(11)(25.5), and P_(11)(22.5) branches of the A ^2 Σ^+(3sσ) state of NO. The branching ratios are dominated by even angular momentum transfer peaks, in agreement with the ΔN+l=odd (ΔN≡N+−Ni ) selection rule. Whereas the calculated photoelectron angular distributions are very branch dependent alignment, the ionic branching ratios are found to be less so. The present calculated results agree well with the experimental results of Allendorf et al.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1063/1.457031DOIUNSPECIFIED
http://jcp.aip.org/resource/1/jcpsa6/v91/i4/p2235_s1PublisherUNSPECIFIED
Additional Information:© 1989 American Institute of Physics. Received 18 April 1989; accepted 5 May 1989. This material is based on research supported by the National Science Foundation under Grant No. CHE-8521391, by AFOSR under Grant. No. 87-0039 and by the Office of Health and Environmental Research of DOE (DE-FG03- 87ER60513). The authors also acknowledge use of the resources of the San Diego Supercomputer which is supported by the National Science Foundation. H.R. gratefully acknowledges support from the NATO Science Fellowship Programme.
Funders:
Funding AgencyGrant Number
NSFCHE-8521391
Air Force Office of Scientific Research (AFOSR)87-0039
Department of Energy (DOE) Office of Health and Environmental Research DE-FG03-87ER60513
NATO Science Fellowship ProgrammeUNSPECIFIED
NSFUNSPECIFIED
Subject Keywords:ROTATIONAL STATES, PHOTOELECTRON SPECTROSCOPY, ANGULAR DISTRIBUTION, RESONANCE, MULTI−PHOTON PROCESSES, PHOTOIONIZATION, NITRIC OXIDE
Classification Code:PACS: 33.60.+q; 33.80.Rv
Record Number:CaltechAUTHORS:20120530-144040127
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20120530-144040127
Official Citation: Rotationally resolved photoelectron angular distributions in resonance enhanced multiphoton ionization of NO H. Rudolph and V. McKoy J. Chem. Phys. 91, 2235 (1989); http://dx.doi.org/10.1063/1.457031
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:31724
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:30 May 2012 22:05
Last Modified:26 Dec 2012 15:17

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