Rudolph, H. and Lynch, D. L. and Dixit, S. N. and McKoy, V. and Huo, Winifred M. (1987) (2+1) resonant enhanced multiphoton ionization of H_2 via the E, F^(1)Σ^+_g state. Journal of Chemical Physics, 86 (4). pp. 1748-1751. ISSN 0021-9606 http://resolver.caltech.edu/CaltechAUTHORS:20120626-114713444
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In this paper, we report the results of ab initio calculations of photoelectron angular distributions and vibrational branching ratios for the (2+1) REMPI of H_2 via the E, F^(1)Σ^+_g state, and compare these with the experimental data of Anderson et al. [Chem. Phys. Lett. 105, 22 (1984)]. These results show that the observed non‐Franck–Condon behavior is predominantly due to the R dependence of the transition matrix elements, and to a lesser degree to the energy dependence. This work presents the first molecular REMPI study employing a correlated wave function to describe the Rydberg–valence mixing in the resonant intermediate state.
|Additional Information:||© 1987 American Institute of Physics. Received 30 September 1986; accepted 7 November 1986. This research was supported by the National Science Foundation under Grant No. CHE8521391. W. M. H. acknowledges support from the NASA Ames Cooperative Agreement NCC 2-147, and H. R. gratefully acknowledges support from the Danish Natural Science Research Council and the Carlsberg Foundation.|
|Subject Keywords:||Hydrogen; multi-photon processes; photoionization; angular distribution; excited states; Franck-Condon principle; rydberg states; photoelectron spectroscopy|
|Classification Code:||PACS: 33.80.Rv; 33.70.Ca; 32.80.Rm|
|Official Citation:||(2+1) resonant enhanced multiphoton ionization of H[sub 2] via the E,F [sup 1] Sigma [sup + ][sub g] state H. Rudolph, D. L. Lynch, S. N. Dixit, V. McKoy, and Winifred M. Huo, J. Chem. Phys. 86, 1748 (1987), DOI:10.1063/1.452174|
|Usage Policy:||No commercial reproduction, distribution, display or performance rights in this work are provided.|
|Deposited By:||Jason Perez|
|Deposited On:||26 Jun 2012 20:53|
|Last Modified:||26 Dec 2012 15:23|
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