Dixit, S. N. and Lynch, D. L. and McKoy, V. (1984) Three-photon resonant four-photon ionization of H_2 via the C^1 ∏_u state. Physical Review A, 30 (6). pp. 3332-3335. ISSN 1050-2947. http://resolver.caltech.edu/CaltechAUTHORS:20120702-092209500
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Ab initio calculations are presented for the vibrational branching ratios in three-photon resonant four-photon ionization of H_2 via the C^1Π_u state. Energy and internuclear distance dependences of the boundfree electronic transition matrix element are explicitly included to estimate deviations from the Franck-Condon approximation. While our calculated branching ratios confirm certain important trends seen experimentally, some differences remain.
|Additional Information:||© 1984 The American Physical Society. Received 4 September 1984; published in the issue dated December 1984. The authors wish to thank R. J. Cave and V. K. Babamov for providing us with the finite element program used for calculating the vibrational wave functions. This research was supported by the National Science Foundation under Grant No. CHE-8218166. The research reported in this paper made use of the Dreyfus-National Science Foundation Theoretical Chemistry Computer which was funded through grants from the Camille & Henry Dreyfus Foundation, the National Science Foundation (Grant No. CHE-7820235), and the Sloan Fund of the California Institute of Technology.|
|Official Citation:||Three-photon resonant four-photon ionization of H2 via the C 1Πu state S. N. Dixit, D. L. Lynch, and V. McKoy pp. 3332-3335|
|Usage Policy:||No commercial reproduction, distribution, display or performance rights in this work are provided.|
|Deposited By:||Ruth Sustaita|
|Deposited On:||02 Jul 2012 18:23|
|Last Modified:||26 Dec 2012 15:27|
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