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On the Theory of Intramolecular Energy Transfer

Marcus, Rudolph A. (1983) On the Theory of Intramolecular Energy Transfer. Faraday Discussions of the Chemical Society , 75 . pp. 103-115. ISSN 0301-7249. http://resolver.caltech.edu/CaltechAUTHORS:20120713-072845152

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Abstract

We consider the distinguishing features of two main types of classical anharmonic motion in molecules, their quantum parallels, and conditions that classical chaos also be sufficient for “quantum chaos”. Implications are considered for experimental reaction rates, R.R.K.M. theory, spectra and a possible type of system for intramolecular laser-selective chemistry. A theory of intramolecular energy transfer between two ligands of a heavy atom is described for a system which may contain many coordinates. It is partly statistical and, for the modes of each ligand which communicate through the heavy atom, dynamical.


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http://dx.doi.org/10.1039/DC9837500103DOIUNSPECIFIED
http://pubs.rsc.org/en/content/articlelanding/1983/dc/dc9837500103PublisherUNSPECIFIED
Additional Information:© 1983 Royal Society of Chemistry. Received 21st December, 1982. I should like to acknowledge the helpful collaboration (identified in the references) with D. W. Noid, M. L. Koszykowski, V. Lopez and T. Uzer on various portions of this research. The research was supported by a grant from the National Science Foundation. I am indebted to Drs. Vicente Lopez and David Wardlaw for their helpful comments. This is contribution no. 6775.
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Caltech Arthur Amos Noyes Laboratory of Chemical Physics6775
Record Number:CaltechAUTHORS:20120713-072845152
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20120713-072845152
Official Citation:On the theory of intramolecular energy transfer Rudolph A. Marcus Faraday Discuss. Chem. Soc., 1983, 75, 103-115 DOI: 10.1039/DC9837500103
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:32403
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:13 Jul 2012 17:00
Last Modified:26 Dec 2012 15:31

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