Ireland, Robert E. and Wilcox, Craig S. and Thaisrivongs, Suvit and Vanier, Noel R. (1979) The generation of C-glycosides through the enolate Claisen rearrangement. Canadian Journal of Chemistry, 57 (13). pp. 1743-1745. ISSN 0008-4042. http://resolver.caltech.edu/CaltechAUTHORS:20120727-080702494
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The [3,3]-sigmatropic rearrangements of silyl ketene acetals obtained from aliphatic esters of furanoid and pyranoid glycals is described. The heterocyclic γ,δ-unsaturated carboxylic acids II are produced in good yields. A new preparation of furanoid and pyranoid glycals is described.
|Additional Information:||© 1979 National Research Council of Canada. Received January 25. 1979. Dedicated to the memory of R. H. F. Manske. This work was made possible by a grant from the National Institutes of Health, Grant No. HL 21367-01.|
|Official Citation:||The generation of C-glycosides through the enolate Claisen rearrangement Robert E. Ireland, Craig S. Wilcox, Suvit Thaisrivongs, Noel R. Vanier Canadian Journal of Chemistry, 1979, 57(13): 1743-1745, 10.1139/v79-278|
|Usage Policy:||No commercial reproduction, distribution, display or performance rights in this work are provided.|
|Deposited By:||Ruth Sustaita|
|Deposited On:||30 Jul 2012 15:52|
|Last Modified:||23 Aug 2016 10:15|
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