Fitz, D. E. and Marcus, R. A. (1975) Semiclassical theory of spectral line shapes. II. Applications to CO, HCl, and OCS, broadened by inert gases. Journal of Chemical Physics, 62 (9). pp. 3788-3796. ISSN 0021-9606 http://resolver.caltech.edu/CaltechAUTHORS:20120731-082134863
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Abstract
The semiclassical theory of spectral line broadening developed in the previous paper of this series is used to calculate the half‐widths and shifts of nonoverlapping rotational spectral lines of CO, HCl, and OCS, broadened by inert gases. Comparisons are made with the available experimental data and with related theoretical analyses, and reasonable agreement is obtained. The method used applies both to fairly quantum systems as well as to the relatively classical ones. A symmetrized semiclassical expression for Wigner 6‐j symbols is given and applied.
| Item Type: | Article | ||||
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| Additional Information: | © 1975 American Institute of Physics. Received 23 January 1975. Supported in part by a grant from the National Science Foundation. | ||||
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| Classification Code: | PACs: 33.70.Ca; 33.20.Ea; 33.20.Fb; 03.65.Sq | ||||
| Record Number: | CaltechAUTHORS:20120731-082134863 | ||||
| Persistent URL: | http://resolver.caltech.edu/CaltechAUTHORS:20120731-082134863 | ||||
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| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||
| ID Code: | 32809 | ||||
| Collection: | CaltechAUTHORS | ||||
| Deposited By: | Tony Diaz | ||||
| Deposited On: | 31 Jul 2012 18:06 | ||||
| Last Modified: | 26 Dec 2012 15:46 |
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