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Mechanism of the fluxional behaviour in (1–5-η-cycloheptadienyl)-(1–5-η-cycloheptatrienyl)iron

Blackborow, J. Richard and Grubbs, Robert H. and Hildenbrand, Knut and von Gustorf, E. A. Koerner and Miyashita, Akira and Scrivanti, Alberto (1977) Mechanism of the fluxional behaviour in (1–5-η-cycloheptadienyl)-(1–5-η-cycloheptatrienyl)iron. Journal of the Chemical Society. Dalton Transactions (22). pp. 2205-2209. ISSN 0300-9246. http://resolver.caltech.edu/CaltechAUTHORS:20120731-104952634

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Abstract

Evidence for a 1.2-shift mechanism of the 1-5-η-cycloheptatrienyl moiety with respect to the central iron atom of the title compound is presented together with absolute assignments of the ^(13)C n.m.r. chemical shifts of the C_(7)H_(7) ring. A low-temperature rocking motion of both rings can be frozen out at -70 °C.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1039/DT9770002205DOIUNSPECIFIED
http://pubs.rsc.org/en/Content/ArticleLanding/1977/DT/dt9770002205PublisherUNSPECIFIED
Additional Information:© 1977 Royal Society of Chemistry. Received 4th August, 1976. We thank Drs. Mark, Bausch, and Grevels at the Institut fur Strahlenchemie for helpful discussions. One of us (R. H. G.) thanks the Alexander von Humboldt Stiftung for a research fellowship.
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Alexander von Humboldt StiftungUNSPECIFIED
Record Number:CaltechAUTHORS:20120731-104952634
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20120731-104952634
Official Citation:Mechanism of the fluxional behaviour in (1–5-η-cycloheptadienyl)-(1–5-η-cycloheptatrienyl)iron J. Richard Blackborow , Robert H. Grubbs , Knut Hildenbrand , E. A. Koerner von Gustorf , Akira Miyashita and Alberto Scrivanti J. Chem. Soc., Dalton Trans., 1977, 2205-2209 DOI: 10.1039/DT9770002205
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:32816
Collection:CaltechAUTHORS
Deposited By: Aucoeur Ngo
Deposited On:01 Aug 2012 14:43
Last Modified:26 Dec 2012 15:46

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