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The Nature of the Chemical Bond. VII. The Calculation of Resonance Energy in Conjugated Systems

Pauling, Linus and Sherman, J. (1933) The Nature of the Chemical Bond. VII. The Calculation of Resonance Energy in Conjugated Systems. Journal of Chemical Physics, 1 (10). pp. 679-686. ISSN 0021-9606. http://resolver.caltech.edu/CaltechAUTHORS:20120801-164037906

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Abstract

The quantum‐mechanical treatment previously applied to benzene, naphthalene, and the hydrocarbon free radicals is used in the calculation of extra resonance energy of conjugation in systems of double bonds, the dihydronaphthalenes and dihydroanthracenes, phenylethylene, stilbene, isostilbene, triphenylethylene, tetraphenylethylene, biphenyl, o, m, and p‐diphenylbenzene, and 1,3,5‐triphenylbenzene. The calculated values, which are in approximate agreement with empirical values from thermochemical data, are used in the discussion of chemical properties and in the formulation of rules regarding conjugation in overlapping systems.


Item Type:Article
Related URLs:
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http://dx.doi.org/10.1063/1.1749226DOIUNSPECIFIED
http://jcp.aip.org/resource/1/jcpsa6/v1/i10/p679_s1PublisherUNSPECIFIED
Additional Information:© 1933 American Institute of Physics. Received 3 July 1933. Contribution No. 370. We are indebted to Professor G. E. K. Branch and to Dr. G. W. Wheland for pointing this out to us.
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Caltech Gates Chemical Laboratory370
Record Number:CaltechAUTHORS:20120801-164037906
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20120801-164037906
Official Citation:The Nature of the Chemical Bond. VII. The Calculation of Resonance Energy in Conjugated Systems Linus Pauling and J. Sherman, J. Chem. Phys. 1, 679 (1933), DOI:10.1063/1.1749226
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:32852
Collection:CaltechAUTHORS
Deposited By: Aucoeur Ngo
Deposited On:02 Aug 2012 14:38
Last Modified:26 Dec 2012 15:47

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