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Relation between State‐Selected or State‐Averaged Cross Sections of Endothermic Reactions and Rate Constants of Exothermic Reactions. Application of Bimolecular Microcanonical Activated Complex Theory

Marcus, R. A. (1970) Relation between State‐Selected or State‐Averaged Cross Sections of Endothermic Reactions and Rate Constants of Exothermic Reactions. Application of Bimolecular Microcanonical Activated Complex Theory. Journal of Chemical Physics, 53 (2). pp. 604-608. ISSN 0021-9606. http://resolver.caltech.edu/CaltechAUTHORS:20120802-133824399

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Abstract

An expression is derived relating state‐selected or state‐averaged molecular beam reaction cross sections of endothermic reactions to observed rate constants for the inverse (exothermic) reactions. An approximation of Anlauf, Maylotte, Polanyi, and Bernstein is used, together with bimolecular microcanonical activated complex theory [R. A. Marcus, J. Chem. Phys. 45, 2138 (1966)].


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http://dx.doi.org/10.1063/1.1674034DOIUNSPECIFIED
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Additional Information:© 1970 American Institute of Physics. Received 16 February 1970. I am particularly indebted to J. C. Polanyi and R. B. Bernstein for their very helpful correspondence and suggestions, and for transmitting to me their results in advance of publication. It is also a pleasure to acknowledge helpful discussions with Dr. Wing Wong of this laboratory. Acknowledgment is made to the donors of the Petroleum Research Fund, administered by the American Chemical Society, for partial support of this research. This research was also supported by a grant from the National Science Foundation.
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Record Number:CaltechAUTHORS:20120802-133824399
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20120802-133824399
Official Citation:Relation between State-Selected or State-Averaged Cross Sections of Endothermic Reactions and Rate Constants of Exothermic Reactions. Application of Bimolecular Microcanonical Activated Complex Theory R. A. Marcus, J. Chem. Phys. 53, 604 (1970), DOI:10.1063/1.1674034
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ID Code:32891
Collection:CaltechAUTHORS
Deposited By: Jason Perez
Deposited On:02 Aug 2012 21:15
Last Modified:26 Dec 2012 15:48

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