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Initiation of Olefin Metathesis: Reaction of Deca-2,8-diene with Catalysts formed from Me_4Sn-WC1_6 and Me_3Al_2Cl_3-(Ph_3P)_2(NO)_2Cl_2Mo

Grubbs, Robert H. and Hoppin, Charles R. (1977) Initiation of Olefin Metathesis: Reaction of Deca-2,8-diene with Catalysts formed from Me_4Sn-WC1_6 and Me_3Al_2Cl_3-(Ph_3P)_2(NO)_2Cl_2Mo. Journal of the Chemical Society. Chemical Communications, 1977 (18). pp. 634-635. ISSN 0022-4936. http://resolver.caltech.edu/CaltechAUTHORS:20120807-142624634

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Abstract

The initial product of the metathesis of deca-2,8-diene with metathesis catalysts formed from either Me_4Sn–WCl_6 or Me_3Al_2Cl_3–(Ph_3P)_2(NO)_2Cl_2Mo is propene; labelling of the terminal groups of the diene and the alkylating agents gives a labelling pattern in the propene that is best explained in terms of generation of a carbene in the initiation step from the alkylating agent.


Item Type:Article
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http://dx.doi.org/10.1039/c39770000634DOIUNSPECIFIED
http://pubs.rsc.org/en/Content/ArticleLanding/1977/C3/c39770000634PublisherUNSPECIFIED
Additional Information:© 1977 Royal Society of Chemistry. Received, 23rd June 1977; Com. 633.
Record Number:CaltechAUTHORS:20120807-142624634
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20120807-142624634
Official Citation:Initiation of olefin metathesis: reaction of deca-2,8-diene with catalysts formed from Me4Sn–WCl6 and Me3Al2Cl3–(Ph3P)2(NO)2Cl2Mo Robert H. Grubbs and Charles R. Hoppin J. Chem. Soc., Chem. Commun., 1977, 634-635 DOI: 10.1039/C39770000634
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:32990
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:07 Aug 2012 22:01
Last Modified:26 Dec 2012 15:52

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