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The Metallacyclopentane-Olefin Interchange Reaction

Grubbs, Robert H. and Miyashita, Akira (1977) The Metallacyclopentane-Olefin Interchange Reaction. Journal of the Chemical Society. Chemical Communications, 1977 (23). pp. 864-865. ISSN 0022-4936. http://resolver.caltech.edu/CaltechAUTHORS:20120808-071724607

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Abstract

Tris(triphenylphosphine)tetramethylenenickel(II) and biscyclopentadienyltetramethylenetitanium, prepared from the reaction of a 1,4-dilithiobutane and the transition metal dihalides react with olefins to produce substituted metallacyclopentanes; the stereochemistry and substitution pattern of the metallocycles formed from propene, octa-1,7-diene, and norbornadiene has been determined.


Item Type:Article
Related URLs:
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http://dx.doi.org/10.1039/C39770000864DOIUNSPECIFIED
http://pubs.rsc.org/en/content/articlelanding/1977/c3/c39770000864PublisherUNSPECIFIED
Additional Information:© 1977 Royal Society of Chemistry. Received, 8th August 1977; Com. 829. The authors thank the National Science Foundation for support of this work.
Record Number:CaltechAUTHORS:20120808-071724607
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20120808-071724607
Official Citation:The metallacyclopentane–olefin interchange reaction Robert H. Grubbs and Akira Miyashita J. Chem. Soc., Chem. Commun., 1977, 864-865 DOI: 10.1039/C39770000864
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:32999
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:08 Aug 2012 14:34
Last Modified:26 Dec 2012 15:52

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