Grubbs, Robert H. and Miyashita, Akira (1977) The Metallacyclopentane-Olefin Interchange Reaction. Journal of the Chemical Society. Chemical Communications, 1977 (23). pp. 864-865. ISSN 0022-4936 http://resolver.caltech.edu/CaltechAUTHORS:20120808-071724607
![[img]](http://authors.library.caltech.edu/style/images/fileicons/application_pdf.png)
|
PDF
- Published Version
See Usage Policy. 142Kb |
Use this Persistent URL to link to this item: http://resolver.caltech.edu/CaltechAUTHORS:20120808-071724607
Abstract
Tris(triphenylphosphine)tetramethylenenickel(II) and biscyclopentadienyltetramethylenetitanium, prepared from the reaction of a 1,4-dilithiobutane and the transition metal dihalides react with olefins to produce substituted metallacyclopentanes; the stereochemistry and substitution pattern of the metallocycles formed from propene, octa-1,7-diene, and norbornadiene has been determined.
| Item Type: | Article |
|---|---|
| Additional Information: | © 1977 Royal Society of Chemistry. Received, 8th August 1977; Com. 829. The authors thank the National Science Foundation for support of this work. |
| Record Number: | CaltechAUTHORS:20120808-071724607 |
| Persistent URL: | http://resolver.caltech.edu/CaltechAUTHORS:20120808-071724607 |
| Related URLs: | |
| Official Citation: | The metallacyclopentane–olefin interchange reaction Robert H. Grubbs and Akira Miyashita J. Chem. Soc., Chem. Commun., 1977, 864-865 DOI: 10.1039/C39770000864 |
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. |
| ID Code: | 32999 |
| Collection: | CaltechAUTHORS |
| Deposited By: | Ruth Sustaita |
| Deposited On: | 08 Aug 2012 14:34 |
| Last Modified: | 26 Dec 2012 15:52 |
Repository Staff Only: item control page
